Synthesis of E,Z-11-tetradecen-1-al

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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568471, 568474, 568485, 568486, C07C 4106, C07C 4529

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047406275

ABSTRACT:
The present invention pertains to a process for making a E,Z-11-tetradecen-1-al containing from 80 to 83 mole percent of the E isomer and from 17 to 20 mole percent of the Z isomer which exhibits pheromone-like activity for the spruce bud worm (choristoneura fumiferana).

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patent: 3959190 (1976-05-01), Weinshenker
patent: 4212830 (1980-07-01), Weisner
patent: 4529825 (1985-07-01), Yamamoto et al.
patent: 4540826 (1985-09-01), Banasiak et al.
patent: 4560792 (1985-12-01), Banasiak
patent: 4579977 (1986-04-01), Drake
patent: 4609498 (1986-09-01), Banasiak et al.
ApSimon, John, The Total Synthesis of Natural Products, vol. 4, p. 19.
"Insect Pheromones; I. Synthesis of Achiral Components of Insect Pheromones", Renzo Rossi, (1977), pp. 821-822.
Agis E. Kydonieus, Insect Suppression with Controlled Release Pheromone Systems, vol. II (1982), p. 178.

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