Synthesis of deuterated opiate glucuronides

Organic compounds -- part of the class 532-570 series – Organic compounds – Carbohydrates or derivatives

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546 44, C07H 1901, C07D48902

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active

059089270

ABSTRACT:
A method of synthesizing deuterated morphine-3.beta.-glucuronide, morphine-6.beta.-glucuronide, and codeine-6.beta.-glucuronide is disclosed. The chemicals are used as internal standards for mass spectrometry analyses of morphine, heroin, and codeine uses. They are also useful in the study of metabolism of morphine and codeine.

REFERENCES:
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Lawson, J.A. et al.: Synthesis of Morphine-d5 and Codeine-d8. J. heterocyclic Chem. vol. 13, pp. 593-595, Jun. 1976.
Rop et al. J. Chromatogr. B 661:245-253(1994).
Hasselstrom et al. Clin. Pharmacokinet. 24(4):344-354 (1993).
Glare et al. Therapeutic Drug Monitoring 13:226-232 (1991).
Carrupt et al. J. Med. Chem. 34, 1272-1275 (1991).
Yoshimura et al. Tetrahedron Lett. 4, 483-486 (1968).

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