Synthesis of daunomycinone and the derivatives thereof

Details Synthesis of daunomycinone and the derivatives thereof Synthesis of daunomycinone and the derivatives thereof

1979-11-07

1983-11-15

Gantz, Delbert E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260365, C07C 4972, C07C 4973

Patent

active

044154984

ABSTRACT:
Regio- and stereospecific method for the preparation of daunomycinone and derivatives thereof utilizing the p-nitrobenzyloxy carbonyl group as a blocking group.

REFERENCES:
patent: 4070382 (1978-01-01), Kende et al.
patent: 4302398 (1981-01-01), Hassall et al.
Tetrahedron Letters, T. Ross Kelly, 1976, No. 43, pp. 3873-3876, "Studies Directed Toward the Synthesis of Adriamycin": A Diels-Alder Approach, Pergamon Press, GB.
Justas Liebigs Annalen Der Chemie, K. Krohn et al., 1979, Nos. 9-12, pp. 2018-2027, "Total Synthese des rac B.-Rhodomycinons".
Chem. Ber., Krohn et al., 1979, vol. 113, pp. 2976-2993, "Synthese neuer Derivate des Daunomycinons und des B.-Rhodomycinons".
Chem. Ber., Krohn et al., 1979, vol. 113, pp. 2640-2649, "Synthese von DL-4-Desmethoxy-7,10-ethanodaunomycinon".
Chem. Ber., Krohn et al., 1979, vol. 112, pp. 3453-3471, "Total Synthese des Daunomycinons".
Chem. Ber., Tolkiehn et al., 1980, vol. 113, pp. 1575-1583, "Regiosepktive Synthese von Digitopurpon und Islandicin durch Komibinierte Diels-Alder-und Marscholk-Renkiton".

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