Synthesis of crystalline ZSM-18

Chemistry of inorganic compounds – Zeolite – Organic compound used to form zeolite

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423709, 423718, C01B 3334

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active

053505700

ABSTRACT:
This invention relates to a new form of crystalline material identified as having the structure of ZSM-18, to a new and useful method for synthesizing said crystalline material and to use of said crystalline material prepared in accordance herewith as a catalyst for organic compound, e.g., hydrocarbon compound, conversion.

REFERENCES:
patent: 3950496 (1976-04-01), Ciric
patent: 4021502 (1977-05-01), Plank et al.
patent: 4851200 (1989-07-01), Ryan
patent: 5290534 (1994-03-01), Tsao
Lok, B. M., "The role of organic molecules in molecular sieve synthesis", Zeolites, vol. 3, 282-291 (no month).
Lawton, S. L. et al., "The Framework Topology of ZSM-18, a Novel Zeolite Containing Rings of Three (Si, Al)-O Species", Science, vol. 247, 1319-1322 (Mar. 1990).
Ciric, J. et al., "Synthesis and Crystal Structure of 2,3,4,5,6,7,8,9-Octahydro-2,2,5,5,8,8-hexamethyl-1-H-benzo[1,2-c:3,4-c':5, 6-c"]tripyrrolium Tribromide Dihydrate, C.sub.18 H.sub.30 N.sub.3.sup.3+ .multidot.3Br.sup.- --2H.sub.2 O.sup.1 ", Journal of the American Chemical Society, 100, 2173-2175, (1978), (no month).

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