Synthesis of codling moth attractant

Details Synthesis of codling moth attractant Synthesis of codling moth attractant

1974-04-01

1976-03-09

Shaver, Paul F.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603472, 2603459, 260456R, 2604658R, 260554, 260595, 260601R, 260615R, 260632R, 260635D, 260999, 260456P, C07F 704, C07F 718

Patent

active

039431576

ABSTRACT:
Sterospecific synthesis of an attractant for the codling moth by reacting sorbic aldehyde with an organo-metallic reagent to yield a 1-ether of trans-8-trans-10-dodecadiene-1,7-diol which is reduced via a 7-sulfonic acid ester to yield an ether of trans-8-trans-10-dodecadiene-1-ol and hydrolyzed to trans-8-trans-10-dodecadien-1-ol. ##SPC1##

REFERENCES:
patent: 2906768 (1959-09-01), Haluska
patent: 3742068 (1973-06-01), Moersch et al.
corey et al., J.A.C.S., 94, p. 6190, (1972).
Eaton et al., J. Org. Chem., 37, p. 1947, (1972).
J.A.C.S., 74, p. 1003, (1952).
J.A.C.S., 74, p. 3024, (1952).

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