Synthesis of carbamate compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

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C07C26902, C07C27160

Patent

active

061334731

ABSTRACT:
Disclosed is a method for the preparation of carbamate compounds substantially free of by-products; the carbamate compounds being prepared by reacting an isocyanate with a hydroxylated compound in the presence of certain catalysts that increase the rate of carbamylation while decreasing the rate of by-product formation.

REFERENCES:
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Database Caplus on STN, Acc. No. 1997:295855, Bryld et al., `Iodopropynyl butylcarbamate: a new contact allergen` Contact Dermatitis (1997), 36(3), p. 156-158 (abstract), 1997.
Database Caplus on STN, Acc. No. 1974:437409, Mori et al., `Carbamates.` JP 49031638 A2 (abstract), Mar. 22, 1974.
Database Derwent, Acc. No. 1987-038636, Salido Garcia, `Ketoxime carbamate(s) prepn. -by reacting oxime with aliphatic isocyanates in liq. state in presence of iron (in)organic salts.` IL 64407 A (abstract), Nov. 30, 1986.
Database Caplus on STN, Acc. No. 1982:423316, Salido Garcia, `Ketoxime carbamates.` ES 497335 (abstract), Jan. 1, 1982.
Chemical Abstracts, vol. 97, No. 3, 1982 XP002116603.
Chemical Abstracts, vol. 120, No. 3, 1993 XP002116602.
"Catalysis of the Isocyanate-Hydroxyl Reaction", J. W. Britain and P. G. Gemeinhardt; Journal of Applied Polymer Science, vol. IV, Issue No. 11, pp. 207-211 (1960).

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