Synthesis of C-glycosylated compounds with the use of a mild, io

Details Synthesis of C-glycosylated compounds with the use of a mild, io Synthesis of C-glycosylated compounds with the use of a mild, io

1992-09-25

1995-05-09

Lilling, Herbert J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Carbohydrates or derivatives

536 111, 536 41, 536 64, C07H 100, C07H 1504, C07G 300

Patent

active

054140749

ABSTRACT:
The invention concerns C-glycosylated derivatives of soft carbon nucleophile compounds, particularly compounds which contain acid-labile structural units. The invention further concerns a mild, cost-effective, non-hazardous and stereoselective method of general application employing a glycal as a glycosyulating agent and iodine as a catalyst for the preparation of C-glycosylated soft carbon nucleophile compounds.

REFERENCES:
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Hacksell, Daves, Jr., Prog. Med. Chem., 1985, vol. 22, pp. 1-65, 1985.
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Sabol, Cregge, Tetrahedron Lett., vol. 30, pp. 6271-6274, 1982.
Herscovici, Muleka, Antonakis, Tetrahedron Lett., vol. 25, pp. 5653-5656, 1984.
Hacksell, Daves, Jr., J. Org. Chem., vol. 48, pp. 2870-2876, 1983.

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