Synthesis of beta phase spherical calcium pyrophosphate powder

Chemistry of inorganic compounds – Phosphorus or compound thereof – Oxygen containing

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C01B 2542

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056769172

ABSTRACT:
A fine, largely beta phase calcium pyrophosphate powder for, e.g., a diffuser coating for the interior surface of lamp envelopes. The powder is useful for electrostatic deposition of such coatings under varying conditions of environmental humidity. A process for the synthesis of the calcium pyrophosphate is also disclosed. Dibasic calcium orthophosphate (monetite) is dissolved in a dilute aqueous hydrochloric acid solution and spray-dried to form a calcium phosphate powder of spherically shaped hollow particles. The calcium phosphate powder is fired in air to convert the calcium phosphate powder to a spherical calcium pyrophosphate powder including the beta phase as a major component and the gamma phase as a minor component. For a diffuser coating, the poder is sonicated to fragment a portion of the hollow particles.

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patent: 3975308 (1976-08-01), Myles
patent: 4721615 (1988-01-01), Griffith et al.

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