Synthesis of azidodinitro compounds

Details Synthesis of azidodinitro compounds Synthesis of azidodinitro compounds

1987-08-05

1990-02-13

Niebling, John F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Azides

204 72, 149 88, C07C11700, C06B 2500, C25B 300

Patent

active

049008510

ABSTRACT:
Provided herein are the compounds 4,4-dinitro-1-butanol, 4-azido-4,4-dinitro-1-butyl acetate and methods for preparing each compound.
4,4-dinitro-1-butanol is prepared by reacting trinitromethane with acrolein, reducing the resulting trinitroaldehyde to provide the corresponding alcohol and reducing the alcohol.
4-azido-4,4-dinitro-1-butyl acetate is prepared by reacting 4,4-dinitro-1-butanol with acetyl chloride to yield the corresponding acetate and reacting the acetate with an alkali metal azide in an electrolysis cell.

REFERENCES:
patent: 3356714 (1967-12-01), Kamlet
patent: 3770795 (1973-11-01), White
patent: 3883377 (1975-05-01), Wright
patent: 4472311 (1984-09-01), Frankel et al.
patent: 4795593 (1989-01-01), Frankel et al.
Chemical Abstract 35191q vol. 69, No. 9 1968 Slovetskii, V. I. et al.
Chemical Abstract 65882r vol. 73, No. 13 1970 Tselinskii et al.
Organic Chemistry 3rd ed. Morrison et al., Allyn and Bacon, Boston 1973.

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