Synthesis of ansa -metallocenes and their parent ligands in...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C585S361000

Reexamination Certificate

active

07064225

ABSTRACT:
The present invention provides a method of making compounds comprising linked cyclopentadienyl and fluorenyl groups, including substituted analogs thereof, which are precursors to ansa-metallocenes comprising bridged cyclopentadienyl and fluorenyl ligands. In one aspect, this invention provides a preparative method for (5-cyclopentadienyl)[5-(2,7-di-tert-butylfluorenyl)]hex-1-ene, and ansa-metallocenes comprising this ligand.

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Ricardo Fierro, “Synthesis and characterization of new one-carbon-bridged titanocene and zirconocene derivatives”, Journal of Organometallic Chemistry, vol. 485, No. 1, Jan. 11, 1995, pp. 11-17.

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