Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal
Patent
1979-04-23
1980-07-29
Ford, John M.
Chemistry of carbon compounds
Miscellaneous organic carbon compounds
C-metal
260538R, 560 62, 560105, 560227, 562471, 562472, 562496, 2602393R, 2603435, 2603436, 2603974, 260326A, 546335, 549 70, 549 79, 562466, 562510, 560192, 560145, 568303, 568316, 568325, 568326, 568335, 568348, 568376, 568393, 568419, 568425, 568433, 568458, 568495, C07D24324
Patent
active
042150442
ABSTRACT:
Process for preparing an organic compound of the formula R.sup.2 R.sup.2 CFC(O)R.sup.3, which process comprises contacting and reacting in a reaction mixture which includes an inert solvent, at a temperature of -40.degree. C. to -100.degree. C., ROF and ##STR1## R is polyfluoroperhaloalkyl of 1-6 carbon atoms or FOCF.sub.2 ; R.sup.1 is hydrocarbyl of 1-6 carbon atoms;
REFERENCES:
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Cady "Proc. Chem. Soc." (1960) pp. 133-138.
Sheppard "Organic Fluorine Chemistry" (Benjamin)(1969) pp. 124-127, 220-221, 230-231, 480-481.
Barton et al. "Chem. Comm." (1968), pp. 804-808.
Hoffman "Chemical Reviews" (1964) vol. 64, pp. 91-98.
Prager et al. "J. Am. Chem. Soc." vol. 87, No. 2, (1965) pp. 230-238.
Thompson "J. Am. Chem. Soc." vol. 89, No. 8, (1967) pp. 1811-1813.
Bond Robert T.
E. I. Du Pont de Nemours and Company
Ford John M.
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