Synthesis of alkyl cycloalkyl dialkoxysilanes

Details Synthesis of alkyl cycloalkyl dialkoxysilanes Synthesis of alkyl cycloalkyl dialkoxysilanes

1987-10-08

1988-10-11

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556470, C07F 708, C07F 718

Patent

active

047772786

ABSTRACT:
Alkyl cycloalkyl dialkoxysilanes (e.g., methyl cyclohexyl dimethoxysilane) can be prepared by reaction of an alkyl trialkoxysilane (e.g., methyl trimethoxysilane) with a Grignard reagent containing the cycloalkyl moiety derived in the final end-product (e.g., a reagent formed by reacting cyclohexyl chloride and magnesium metal). The reaction is run in the absence of ether solvent, the Grignard reagent is preferably formed in situ by the reaction of magnesium metal and cyclohexyl halide, and agitation is used to promote the reaction. Advantageously, a catalyst, such as iodine, is used to promote the reaction.

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Chemical Abstracts, vol. 47, 2724g.
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