Synthesis of 4-demethoxydaunomycinone

Details Synthesis of 4-demethoxydaunomycinone Synthesis of 4-demethoxydaunomycinone

1982-12-20

1984-05-15

Trousof, Natalie

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

2603511, 260365, C07C 5027, C07C 8710, C07C 5036

Patent

active

044487240

ABSTRACT:
A synthesis of 4-demethoxydaunomycinone and its derivatives from the known compound 9-acetyl-6,11-dihydroxy-7,8,9,10-tetrahydro-5,12-naphthacenedione. 4-Demet hoxydaunomycinone may be converted to 4-demethoxydaunorubicin which is an anthracycline derivative known to have antitumor activity.

REFERENCES:
patent: 4070382 (1978-01-01), Kende et al.
patent: 4116981 (1978-09-01), Kende
patent: 4154745 (1979-05-01), Kende et al.

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