Synthesis of 2,3-disubstituted-2-cyclopentenones via lithiomethy

Details Synthesis of 2,3-disubstituted-2-cyclopentenones via lithiomethy Synthesis of 2,3-disubstituted-2-cyclopentenones via lithiomethy

1990-01-24

1991-06-11

Reamer, James H.

Organic compounds -- part of the class 532-570 series

Organic compounds

Oxygen containing

568312, 568 42, 549 78, C07C 4565

Patent

active

050233823

ABSTRACT:
2,3-disubstituted-2-cyclopenenones (such as cisjasmone) are prepared by (a) reacting an alkl 2-chloro-2,3-disubstituted-3-butenoate with a lithiomercaptan compound, (b) subjecting that product to reductive dehydrosulfurization. Methods of preparing the reactants are also disclosed.

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