Synthesis of 2,2-dimethyl-4-methyleneglutaric acid and derivativ

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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560190, 560193, 560196, 560198, 560202, 562595, C07C12000, C07C12100, C07C 69593, C07C 67465, C07C 51353, C07C 5713

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045473234

ABSTRACT:
The process comprises dimerizing methacrylic acid derivatives in the presence of an organic Co(II) glyoxime to produce 2,2-dimethyl-4-methyleneglutaric acid and/or derivatives thereof. Methacrylic acid derivatives include methacrylic acid or derivatives of methacrylic acid. The composition produced by the process comprises a glutaric dimer acid which can be further polymerized to form high molecular weight polymer useful as a binder in protective coatings.

REFERENCES:
patent: 2232785 (1941-02-01), Howk
patent: 3074999 (1963-01-01), Rauhut et al.
patent: 3227745 (1965-01-01), McClure
patent: 3322819 (1967-05-01), Schreyer

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