Synthesis of 1-aminoanthraquinone

Organic compounds -- part of the class 532-570 series – Organic compounds – Polycyclo ring system containing anthracene configured ring...

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552208, 568319, C07C72534, C07C 268

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active

051304481

ABSTRACT:
1-Aminoanthraquinone (1-AAQ) is synthesized by the condensation of 2-substituted benzoic acid and xylene to yield 2-substituted-dimethylbenzophenone, subsequent oxidation of the methyl groups, ring closure to form a 1-substituted anthraquinone carboxylic acid, replacement of the 1-substituent with ammonia, and decarboxylation.

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"Synthesis of Chloro Derivatives of 2-Anthraquinonecarboxylic Acid", N. S. Dokunikhin et al, Scientific Research Institute of Organic Intermediates and Dyes, Translated from Zhurnal Obshchei Khimii, vol. 31, No. 12, pp. 3985-3987, Dec. 1961.
"Liquid-Phase Catalytic Oxidation of 3,5-Dimethyldiphenylmethane and Its Methyl-, Chloro-, and Nitro-Substituted Derivatives", Yu. V. Pozdnyakovich et al, Rubezhnoe Branch, Scientific-Research Institute of Organic Intermediates and Dyes, pp. 349-359, Translated from Zhurnal Organicheskoi Khimii, vol. 19, No. 2, pp. 398-403, Feb. 1983.
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"Anthraquinone Derivatives", Kirk-Othmer Encyclopedia of Chemical Technology, vol. 2, pp. 716-719 and 725-728.

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