Synthesis method of physiologically active delta-lactone

Details Synthesis method of physiologically active delta-lactone Synthesis method of physiologically active delta-lactone

1994-06-09

1995-10-31

Ivy, C. Warren

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30930

Patent

active

054630851

ABSTRACT:
A synthesis method of physiologically active .delta.-lactone, which comprises addition-reacting diethyl methylmalonate and methacrolein in the presence of a base.

REFERENCES:
patent: 4864056 (1989-09-01), Senda et al.
R-3-Methyl-y-butyrolactone as a Template for the Syntheses of (+)-Invictolide, Ziegler et al, Tetrahedron Letters, vol. 27, No. 11, pp. 1229-1232, (1986).
Isolation of the Trail Recruitment Pheromone of Solenopsis invicta, Meer et al, Journal of Chemical Ecology, vol. 14, No. 3, pp. 825-838, (1988).
Synthesis of Homofarnesenes: Trail Pheromone Components of the Fire Ant, Solenopsis Invicta, Alvarez et al, Tetrahedron, vol. 43, No. 13, pp. 2897-2900, (1987).
Synthesis of (-)-Invictolide, the Peromone Component of the Red Imported Fire Ant, Senda et al, Agric. Biol. Chem., 51(5), pp. 1379-1384, (1987).
Synthesis and Stereochemistry of Tetrahydro-3,5-Dimethyl-6-(1-Methylbutyl)-2H-Pyran-2-One, etc., Rocca et al, Tetrahedron Letters, vol. 24, No. 18, pp. 1893-1896, (1983).

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