Synthesis gas production by steam reforming using catalyzed...

Details Synthesis gas production by steam reforming using catalyzed... Synthesis gas production by steam reforming using catalyzed...

2001-03-29

2004-06-08

Langel, Wayne A. (Department: 1754)

Compositions

Gaseous compositions

Carbon-oxide and hydrogen containing

C423S652000, C423S653000, C423S654000

Reexamination Certificate

active

06746624

ABSTRACT:

The present invention is directed to the production of synthesis gas by steam reforming of a hydrocarbon feedstock in contact with catalyzed hardware.
The term catalyzed hardware is used for a catalyst system where a layer of catalyst is fixed on a surface of another material, e.g. metallic surfaces. The other material serves as the supporting structure giving strength to the system. This allows to design catalyst shapes which would not have sufficient mechanical strength in itself.
Synthesis gas is produced from hydrocarbons by steam reforming by the reactions (1)-(3):
C
n
H
m
+n
H
2
O→
n
CO+(
n+m/
2)H
2
(−&Dgr;H
298
o
<0)  (1)
CO+H
2
O
CO
2
+H
2
(−&Dgr;H
298
o
=41 kJ/mole)  (2)
CH
4
+H
2
O
CO+3H
2
(−&Dgr;H
298
o
=−206 kJ/mole)  (3)
State of the art steam reforming technology makes use of reforming catalyst in the form of pellets of various sizes and shapes. The catalyst pellets are placed in fixed bed reactors (reformer tubes). The reforming reaction is endothermic. In conventional reformers, the necessary heat for the reaction is supplied from the environment outside the tubes usually by a combination of radiation and convection to the outer side of the reformer tube. The heat is transferred to the inner side of the tube by heat conduction through the tube wall and is transferred to the gas phase by convection. Finally, the heat is transferred from the gas phase to the catalyst pellet by convection. The catalyst temperature can be more than 100° C. lower than the inner tube wall temperature at the same axial position of the reformer tube.
It has been found that heat transport is more efficient when catalyzed hardware is used in the steam reforming process. The heat transport to the catalyst occurs by conduction from the inner tube wall. This is a much more efficient transport mechanism than the transport by convection via the gas phase. The result is that the temperatures of the inner tube wall and the catalyst are almost identical (the difference below 5° C.). Furthermore, the tube thickness can be reduced, see below, which makes the temperature difference between the inner and outer side of the reformer tube smaller. It is hence possible to have both a higher catalyst temperature and a lower tube temperature, all other conditions being the same when replacing the conventional reformer tubes with catalyzed hardware tubes. A low outer tube wall temperature is desirable since it prolongs the lifetime of the tube. A high catalyst temperature is advantageous since the reaction rate increases with temperature and since the equilibrium of reaction (3) is shifted to the right hand side resulting in a better utilisation of the feed.
Pressure drop in the catalyzed reformer tube is much lower than in the conventional case for the same tube diameter. This enables the use of reactor tubes with a smaller diameter and still maintaining an acceptable pressure drop. Smaller tube diameter results in an increased tube lifetime, tolerates higher temperatures and reduces the tube material consumption.
Finally, the catalyst amount is reduced when using catalyzed hardware reformer tubes compared to the conventional reformer with a fixed bed of reforming catalyst.


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