Synthesis and evaluation of new cyanine dyes as minor groove...

Chemistry: molecular biology and microbiology – Measuring or testing process involving enzymes or... – Involving nucleic acid

Reexamination Certificate

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C546S152000, C546S270100, C546S271700, C546S273400

Reexamination Certificate

active

07378240

ABSTRACT:
The present invention relates to new cyanine dyes according to the formula (I), wherein A1and A2are each independently O, S, or N, and R is H or a carbohydrate that may contain a hetero atom, and m is 0 to 5, and n is 0 to 5.

REFERENCES:
patent: 5656449 (1997-08-01), Yue
patent: WO 01/94473 (2001-12-01), None
patent: WO 02/090443 (2002-11-01), None
Carlsson et al., Optical and photophysical properties of the oxazole yellow DNA probes YO and YOYO, J. Phys. Chem., 1994, pp. 10313-10321, vol. 98.
Colson et al., Electric linear dichroism as a new tool to study sequence preference in drug binding to DNA, Biophysical Chemistry, 1996, pp. 125-140, vol. 58.
Deligeorgiev et al., Preparation of Intercalating Dye Thiazole Orange and Derivatives, Dyes and Pigments, 1995, pp. 315-322, vol. 29, No. 4.
Gurrieri et al., Direct Visualization of individual DNA Molecules by Fluorescence Microscopy: Characterization of the Factors Affecting Signal/Background and Optimization of Imaging Conditions Using YOYO, Analytical Biochemistry, 1997, pp. 44-53, vol. 249.
Haugland, Nucleic Acid Stains, Handbook of Fluorescent Probes and Research Chemicals, 1996, pp. 144-152, 6th Edition, No. 8.
Isacsson et al., Solid-phase synthesis of asymmetric cyanine dyes, Tetrahedron Letters, 2001, pp. 3207-3210, vol. 42.
Jorgenson et al., Interaction of Hoechst 33258 with Repeating Synthetic DNA Polymers and Natural DNA, Journal of Biomolecular Structure & Dynamics, 1988, pp. 1005-1023, vol. 5, No. 5.
Kapuscinski et al., Fluorescent complexes of DNA with DAPI 4′6-diamidine-2-phenyl indole.2HCI or DCI 4′,6-dicarboxyamide-2-phenyl indole, Nucleic Acids Res., 1978, pp. 3775-3799, vol. 5, No. 10.
Kubista et al., Characterization of Interaction between DNA and 4′,6-Diamidino-2-phenylindole by Optical Spectroscopy, Biochemistry, 1987, pp. 4545-4553, vol. 26.
Larsson et al., Characterization of the Binding of YO to [Poly(dA-dT)]2and [Poly (dG-dC)]2.and of the Fluorescent Properties of YO and YOYO Complexed with the Polynucleotides and Double-Stranded DNA, Biopolymers, 1995, pp. 153-167, vol. 36.
Larsson et al., Characterization of the Binding of the Fluorescent Dyes YO and YOYO to DNA by Polarized Light Spectroscopy, 1994, pp. 8459-8465, vol. 116.
Lee et al., Thiazole Orange: A New Dye for Reticulocyte Analysis, Cytometry, 1986, pp. 508-517, vol. 7.
Lyng et al., The CD of Ligand—DNA Systems. 2. Poly (dA-dt) B-DNA, Biopolymers, 1992, pp. 1201-1214, vol. 32.
Matsuzawa et al., Change of the Higher Order Structure in a Giant DNA Induced by 4′, 6-Diamidino-2-Phenylindole as a Minor Groove Binder and Ethidium Bromide as an Intercalator, Nucleosides & Nucleotides, 1994, pp. 1415-1423, vol. 13, No. 6 & 7.
Mikheikin et al., Binding of Symmetrical Cyanine Dyes into the DNA Minor Groove, Journal of Biomolecular Structure & Dynamics, 2000, pp. 59-72, vol. 18, No. 1.
Mital et al., Synthesis of Some 5-Substituted 2-Aminobenzenethiols and their Conversion into Phenothiazines via Smile Rearrangement, J. Chem. Soc., 1969, pp. 2148-2150.
Naim et al., Studies in antiparasitic agents: Part 17—Synthesis of 2-acylamino-6-substituted-benzthiazoles as potential anthelmintic agents, Indian Journal of Chemisty, 1991, pp. 494-498, vol. 30B.
Neidle, Crystallographic Insights into DNA Minor Groove Recognition by Drugs, Biopolymers, 1997, pp. 105-121, vol. 44.
Netzel et al., Base-Content Dependence of Emission Enhancements, Quantum Yields, and Lifetimes for Cyanine Dyes Bound to Double-Strand DNA: Photophysical Properties of Monomeric and Bichromophoric DNA Stains, J. Phys. Chem., 1995, pp. 17936-17947, vol. 99.
Norden et al., Linear dichroism spectroscopy of nucleic acids, Quarterly Review of Biophysics, 1992, pp. 51-170, vol. 25, No. 1.
Nygren et al., The Interactions Between the Fluorescent Dye Thiazole Orange and DNA, Biopolymers, 1998, pp. 39-51, vol. 46.
Ogul'Chansky et al., Interactions of cyanine dyes with nucleic acids. XXIV. Aggregation of monomethine cyanine dyes in presence of DNA and its manifestation in absorption and fluorescence spectra, Spectrochimica Acta—Part A, 2001, pp. 1525-1532, vol. 57.
Petty et al., Thermodynamic Characterization of the Association of Cyanine Dyes with DNA, J. Phys. Chem. B, 2000, pp. 7221-7227, vol. 104.
Rye et al., Stable fluorescent complexes of double-stranded DNA with bis-intercalating asymmetric cyanine dyes: properties and applications, Nucleic Acids Res., 1992, pp. 2803-2812, vol. 20, No. 11.
Seifert et al., Spontaneous Assembly of Helical Cyanine Dye Aggregates on DNA Nanotemplates, J. Am. Chem. Soc., 1999, pp. 2987-2995, vol. 121.
Singer et al., Characterization of PicoGreen Reagent and Development of a Fluorescence-Based Solution Assay for Double-Stranded DNA Quantitation, Analytical Biochemistry, 1997, pp. 228-238, vol. 249.
Svanvik et al., Light-Up Probes: Thiazole Orange-Conjugated Peptide Nucleic Acid for Detection of Target Nucleic Acid in Homogeneous Solution, Analytical Biochemistry, 2000, pp. 26-35, vol. 281.
Wilson et al., Binding of 4′,6-Diamidino-2-phenylindole (DAPI) to GC and Mixed Sequences in DNA: Intercalation of a Classical Groove-Binding Molecule, J. Am. Chem. Soc., 1989, pp. 5008-5010, vol. 111.
Yoshinaga et al., Intercalating Fluorescence Dye YOYO-1 Prevents the Folding Transition in Giant Duplex DNA, Biochemical and Biophysical Research Communications, 2001, pp. 264-267, vol. 286.
Zhou et al., Blue Sensitizing Dyes: Synthesis, Spectroscopy, and Performance in Photographic Emulsions, Journal of Imaging Science and Technology, 1995, pp. 244-252, vol. 39, No. 3.
Zubarovskii et al., Asymmetric imidacarbocyanines with hetaryls as substituents, Chemical Abstracts, 1975, pp. 851-854, vol. 41, No. 8.
Prenna et al., “Automated determination of DNA cellular content (Feulgen) improved by using BBT-SO2in flow cytofluorometry,” Pulse-Cytophotometry, 1976, pp. 88-95.
Latt et al., “New Fluorochromes, Compatible with High Wavelength Excitation, for Flow Cytometric Analysis of Cellular Nucleic Acids,” Cytometry, vol. 5, No. 4, pp. 339-347, Jul. 1984.
Singh et al., “Synthetic Utility of Catalytic Fe(III)/Fe(II) Redox Cycling Towards Fused Heterocycles: A Facile Access to Substituted Benzimidazole, Bis-benzimidazole and Imidazopyridine Derivatives,” Synthesis, 2000, No. 10, pp. 1380-1390.

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