Synthesis and copolymerization of asymmetric polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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525353, 5253591, 5253594, 5253595, 5253596, 525377, 525379, 525384, 525309, 525319, 5263487, C08F11010

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active

045241880

ABSTRACT:
The invention encompasses the synthesis of telechelic, i.e., terminally functional, macromolecular monomers (macromers) and their subsequent homo- and copolymerization. The macromers produced are asymmetric, having dissimilar head and tail groups which provide independent reaction sites. Macromers include .alpha.-phenyl-.omega.-t-chloropolyisobutylene, which can be reacted to form poly(methyl methacrylate-g-isobutylene). The graft copolymers provide novel physical properties which are the product of the respective grafts.

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patent: 4442261 (1984-04-01), Kennedy et al.

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