Synthesis and application of photosensitive pentacene...

Active solid-state devices (e.g. – transistors – solid-state diode – Organic semiconductor material

Reexamination Certificate

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C257S228000, C257S431000, C438S780000, C430S270100

Reexamination Certificate

active

07053401

ABSTRACT:
Soluble, photosensitive precursors of pentacene are synthesized by a one-step Diels-Alder reaction of pentacene with N-sulfinylamides. These precursors may include a photopolymerizable group, which renders the pentacene precursor as a negative tone resist. The pentacene precursor may also include an acid-sensitive protecting group, which in the presence of a photoacid generator and upon exposure to UV light, is removed and the product becomes base soluble. Patterned pentacene thin films may be obtained by exposure to UV light through a mask and/or heating, and used as an active channel material for an organic field effect transistor.

REFERENCES:
patent: 6452207 (2002-09-01), Bao
patent: 2003/0144562 (2003-07-01), Afali-Ardakani et al.
Afzali, A.; Dimitrakopoulos, C.D.;Breen, T.L.; High-Performance, Solution Processes Organic Thin Film Transistors from a Novel Pentacene Precursor, J. American Chemical Society, Jul. 9, 2002; No. 124, pp. 8812-8813.
Herwig, P.T.; Müllen, K.; A Soluble Pentacene Precursor: Synthesys, Solid-State Conversion into Pentacene and Application in a Field-Effect Transistor; Advanced Materials, 1999, vol. 11, No. 6, pp. 480-483.

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