Syndiotactic styrene polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526251, 526274, 526279, 526286, 526287, 526293, 526346, 5263471, 5263472, 526334, 526326, 526336, 526160, C08F 1234, C08F 1214, C08F 1208

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055021336

ABSTRACT:
Styrene homo-or-co- polymers, the stereoregularity of which is mainly syndiotactic are disclosed, having repeating unit or two or more different repeating units defined by a general formula (I): ##STR1## wherein each R may be the same or different. And a method of preparation of syndiotactic copolymers wherein there are two different repeating units represented by formula (I); wherein the polymerization is carried out with a catalyst comprising (a) a titanium compound and (b) a contact product of an organoaluminum compound and a condensing agent such as water.

REFERENCES:
patent: 3009206 (1961-11-01), Salyer et al.
patent: 3051690 (1962-08-01), Vandenberg
patent: 3070577 (1962-12-01), Stogryn et al.
patent: 3207740 (1965-09-01), Cheney
patent: 3242099 (1966-03-01), Manyik et al.
patent: 3414553 (1968-12-01), Kern
patent: 3489737 (1970-01-01), Natta et al.
patent: 3534006 (1970-10-01), Kamaishi et al.
patent: 3639332 (1972-02-01), Coover, Jr. et al.
patent: 4404344 (1983-09-01), Hansjo/ rg et al.
patent: 4456695 (1984-06-01), Nimura et al.
patent: 4522982 (1985-06-01), Ewen
patent: 4542199 (1985-09-01), Kaminsky et al.
patent: 4680353 (1987-07-01), Isihara et al.
patent: 4774301 (1988-09-01), Campbell, Jr. et al.
patent: 5142005 (1992-08-01), Albizzati et al.
patent: 5189125 (1993-02-01), Ishihara et al.
patent: 5252693 (1993-10-01), Ishihara et al.
Bovey et al., J. Chem. Phys., 38, 1026 (1963). (Article unavailable).
"Copolymerization 1, Reaction Analysis," pp. 6-8, ed. K. Gakkai, Tokyo, Japan. (Article unavailable).
"Crystalline Syndiotactic Polystyrene," N. Ishihara, T. Seimiya, M. Kuramoto and M. Uoi, Macromolecules, vol. 19, pp. 2464-2465 (Sep. 1986).
"Isotactic Polymers," G. Natta, Makromol. Chem., 16, 213 (1955).
"Metallocenes--The Race to Breed a New Generation of Catalysts," Wood, Chem. Week, Jul. 1-8, 1992, pp. 42-44.
Nakada et al., Kougyo Kagaku, 68, 858-864 (1965).
Natta et al., Nuovo Cimento, 15, Suppl. 1, 40 (1960). (Article unavailable).
"Reinvestigation of the Stereoregularity of Polystyrene by 100 MHz .sup.13 C NMR Spectroscopy," Tokiji Kawamura, Toshiyuki Uryu and Kei Matsuzaki, Makromol. Chem. Rapid Commun. 3, pp. 661-665 (1982).
"Selective Synthesis of Syndiotactic Polystyrene," Alfonso Grassi, Claudio Pellecchia, Pasquale Longo and Adolfo Zambelli, Gazzetta Chimica Italiana, 117, pp. 249-250 (1987).
"Stereoregularity of Polystyrene Derivatives 2," Tokiji Kawamura, Toshiyuki Uryu and Kei Matsuzaki, Makromol. Chem. 183, pp. 143-151 (1982).
"Stereoregularity of Polystyrene Derivatives 3," Tokiji Kawamura, Toshiyuki Uryu and Kei Matsuzaki, Makromol. Chem. 183, pp. 153-162 (1982).
"Stereoregularity of Polystyrene Derivatives 4," Tokiji Kawamura, Toshiyuki Uryu and Kei Matsuzaki, Makromol. Chem. 183, pp. 1647-1652 (1982).
"Stereospecific Polymerization and Isotactic Polymers of Vinyl Aromatic Monomers," Natta et al., Makromol. Chem. 28, 253 (1958).
"The Tacticity of Poly-.alpha.-Methylstyrenes Produced by Cationic and Anionic Polymerization," Dietrich Braun et al., Berichte der Bunsengesellschaft, vol. 68, No. 10, pp. 959-964 (1964).
Vysokomol Soedin, B, 1973, 15(8), pp. 612-615 and translation.
Zambelli et al., Macromolecules 1989, 22, pp. 2129-2130. (Article unavailable).
Kawamura et al, "Stereoregularity of Polystyrene Derivatives, 1 . . . " Makromol. Chem., 183, 125 (1982).

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