Symmetrical conjugated diene and polyene synthesis via vinylmerc

Details Symmetrical conjugated diene and polyene synthesis via vinylmerc Symmetrical conjugated diene and polyene synthesis via vinylmerc

1976-04-30

1977-05-31

Gantz, Delbert E.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

260453R, 260563R, 260586R, 260617R, 260666PY, 260668R, 260680B, C07C 100

Patent

active

040269574

ABSTRACT:
Vinylmercuric halide salts undergo reaction with palladium (II) dimerization promoting agents, preferably in a highly polar organic solvent at low temperatures to provide essentially quantative yields of conjugated dienes. Importantly, the reaction is stereospecific and is especially valuable for synthesis of functionally substituted dienes and symmetrical polyenes.

REFERENCES:
patent: 3361840 (1968-01-01), Kohll et al.

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