Switchable volume hologram materials and devices

Details Switchable volume hologram materials and devices Switchable volume hologram materials and devices

2005-12-20

2008-08-26

Wu, Shean C (Department: 1795)

Radiation imagery chemistry: process, composition, or product th

Holographic process, composition, or product

Composition or product or process of making the same

C430S020000, C359S015000, C252S299010

Reexamination Certificate

active

07416818

ABSTRACT:
A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved.

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