Organic compounds -- part of the class 532-570 series – Organic compounds – Phosphorus esters
Patent
1998-05-29
1999-07-13
Ambrose, Michael G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Phosphorus esters
558165, 558186, C07F 909
Patent
active
059228970
ABSTRACT:
A process for the preparation of surfactants is described comprising reacting a phosphorus acid ester of the following Formula (IV) ##STR1## wherein R.sup.t is aryl, R.sup.2 is alkyl or aryl, with a hydrophilic polyoxyalkylene of the following Formulas (VIII), or (IX) ##STR2## wherein R.sup.3 is alkyl and A is a hydrophilic polyoxyalkylene chain, and which reaction results in an intermediate compound Formulas (XI), (XII), or (XIII); ##STR3## reacting the intermediate compound selected from the group consisting of Formulas (XI) through (XIII), with a hydroxylic compound R.sup.1 -OH (X) to yield surfactant precursors comprised of Formulas (V), (VI), and (VII), respectively: ##STR4## and, oxidizing said phosphorus ester-linked surfactant precursors selected from the group consisting of Formulas (V), (VI) and (VII), with an oxidizing agent to produce the surfactants.
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Goodbrand H. Bruce
Hu Nan-Xing
Ambrose Michael G.
Palazzo E. O.
Xerox Corporation
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