Stock material or miscellaneous articles – Composite – Of silicon containing
Reexamination Certificate
2001-04-26
2004-02-10
Nakarani, D. S. (Department: 1773)
Stock material or miscellaneous articles
Composite
Of silicon containing
C351S16000R, C351S16000R, C359S581000, C428S520000, C428S522000, C523S106000, C523S107000, C523S108000
Reexamination Certificate
active
06689480
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a method for surface treatment of a plastic article and a surface-treated plastic article. In particular, the present invention relates to a surface-treated plastic article exhibiting superior hydrophilicity, that is, wettability, and superior deposition resistance, that is, lipid-fouling resistance, etc., which has been surface-treated without degradation of properties as the plastic article. Specifically, the surface-treated plastic article according to the present invention is appropriately used for contact lenses and intraocular lenses, or medical devices, such as catheters and artificial kidneys.
2. Description of the Related Art
In recent years, plastic articles have been proposed for many purposes. Among those, various plastic articles containing silicon or fluorine have been proposed for contact lenses because of the excellent oxygen permeability.
The plastic articles containing silicon or fluorine are, however, insufficient in wettability, and an improvement in the wettability has been demanded. In particular, various methods have been proposed in order to improve the lens performance (fitting characteristics, comfort etc.) in eyes by surface modification of contact lenses. For example, in U.S. Pat. No. 4,214,014, a method, in which the wettability is imparted to a contact lens by a plasma treatment in an oxygen atmosphere, is disclosed. In JP-A-8-227001, a method, in which the wettability is imparted to a silicone containing hydrogel contact lens by a plasma treatment in the atmosphere of oxygen and/or carbon dioxide gas, is disclosed.
The aforementioned conventional techniques improved the wettability, however, there have been problems in that the material quality of the plastic article was degraded due to the oxygen gas. In addition to this, there was a significant problem in that the wettability varied with time due to washings and a long term of use so as to become hydrophobic.
SUMMARY OF THE INVENTION
The present invention includes a method for surface treatment of the plastic article, to get good and stable wettability of the surface without variation over time, thus keeping the good inherent properties of the plastics unchanged. Accordingly, it is an object of the present invention to provide a surface-treated plastic article having high transparency and high oxygen permeability, exhibiting excellent wettability and superior mechanical properties, and appropriately used for, in particular, contact lenses and medical devices such as catheters. It is another object of the present invention to provide a method of surface treatment of the aforementioned plastic article.
The present invention resides in the following features in order to achieve the aforementioned objects. According to a first aspect of the present invention, a method for surface treatment of a plastic article, in which the plastic article is treated with at least one kind of aqueous solutions of polymers having a weight average molecular weight of 200 or more, is provided. According to a second aspect of the present invention, a plastic article, surface-treated with the polymer having a weight average molecular weight of 200 or more, is provided. According to a third aspect of the present invention, a surface-treated plastic article, including a thin layer composed of a polymer complex on the surface, is provided.
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Shimoyama Naoki
Uemura Tadahiro
Yokota Mitsuru
Morrison & Foerster / LLP
Nakarani D. S.
Toray Industries Inc.
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