Surface imprinted films with carbon nanotubes

Semiconductor device manufacturing: process – Chemical etching – Liquid phase etching

Reexamination Certificate

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C438S800000, C438S508000, C977S742000, C977S842000, C977S845000

Reexamination Certificate

active

07119028

ABSTRACT:
A film surface imprinted with nanometer-sized particles to produce micro- and/or nano-structured electron and hole collecting interfaces, including: at least one substrate; at least one photoabsorbing conjugated polymer (including polybutylthiophene (pbT)) applied on a substrate, nanometer-sized particles including multiwalled carbon nanotubes (MWNT) to produce a charge separation interface; at least one transparent polymerizable layer, wherein the MWNT are embedded in the conjugated polymer to produce mixture and applied on a substrate to form a MWNT bearing surface film layer to form a stamp surface which is imprinted into the surface of the polymerizable film layer to produce micro- and/or nano-structured electron and hole collecting interfaces; polymerizing the polymerizable film layer to form a conformal gap between the MWNT stamp surface and the surface of the polymerizable film layer, and filling the gap with a photoabsorbing material to promote the generation of photoexcited electrons and transport to the charge separation interface.

REFERENCES:
patent: 6383923 (2002-05-01), Brown et al.
patent: 6517995 (2003-02-01), Jacobson et al.
Michael C. McAlpine, Robin S. Friedman, and Charles M. Lieber, Nano Letters 2003, 3(4), 443-445, “Nanoimprint Lithography for Hybrid Plastic Electronics”.
F. L. Dickert and O. Hayden, Analytical Chemistry, vol. 74, Issue 6 (Mar. 15, 2002), 1302-1306, “Bioimprinting of Polymers and Sol-Gel Phases. Selective Detection of Yeasts with Imprinted Polymers”.

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