Supramolecular complexes as photocatylysts for the...

Chemistry of inorganic compounds – Hydrogen or compound thereof – Elemental hydrogen

Reexamination Certificate

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Reexamination Certificate

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07122171

ABSTRACT:
Supramolecular complexes designed to produce hydrogen from water are provided. The supramolecular complexes absorb visible light and undergo charge transfer, leading to the collection of electrons at a reactive metal center, where the electrons reduce water to hydrogen. The complex remains intact during electron collection and hydrogen production.

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patent: 2005/0232858 (2005-10-01), Hampden-Smith et al.
Peng, Xiaojun et al. “New oxygen-evolving complexes in artificial photosynthesis system splitting water into oxygen and hydrogen.” Preprints of Symposia-American Chemical Society, Division of Fuel Chemistry (2004), 49(2); pp. 974-975.
Amouyal, Edmond. “Water splitting: from molecular to supramolecular photochemical systems.” Homogeneous Photocatalysis, Wiley Series in Photoscience and Engineering, Apr. 1997; 426 pages.
Cecal, Al. et al. “On hydrogen production by catalytic split of water.” Analele Siintifice ale Universitatii, vol. 9, 2001; pp. 15-20.
Cecal, Alexandru et al. “Radiolytic splitting of water molecules in the presence of some supramolecular compounds.” Jouranl of the Serbian Chemical Society, vol. 68(7), 2003, pp. 593-598.

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