Supported vinyl chloride emulsion (co) polymers and process for

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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524457, 524458, 524460, 524461, 524527, 525193, 5253307, 5253315, 5253333, 5253334, 525902, C08F25904, C08F25906, C08F 1400, C08F 1416, C08F11416

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060204389

ABSTRACT:
An emulsion polymer comprising as one of its components a graft copolymer of a residual aromatic monomer-free support resin polymer and a vinyl chloride (co)polymer is disclosed. The emulsion polymer is prepared using a two-stage process. In the first stage, a chasing monomer is reacted in the presence of a support resin polymer having at least one aromatic monomer to form an polymer which is free of residual monomer and has monomeric units derived from the aromatic monomer(s). In a second stage, the vinyl chloride emulsion (co)polymer is made in situ in a reaction mixture comprising the polymer which is free of residual monomer. An extensive grafting at the second stage yields a novel water dispersible graft copolymer containing both styrene and vinyl chloride.

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