Supported polymerisation catalysts

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

Reexamination Certificate

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C526S170000, C526S161000, C526S172000, C526S134000, C526S129000, C526S130000, C526S348000, C526S348500, C526S348600, C526S348200, C526S351000, C526S352000, C526S943000, C526S901000, C502S118000

Reexamination Certificate

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07452948

ABSTRACT:
An improved method for the preparation of a supported polymerisation catalyst system comprises the combination of (i) a porous support (ii) a polymerisable monomer, (iii) a polymerisation catalyst, and (iv) a cocatalyst, characterised in that the polymerisable monomer is added to the porous support before addition of one or both of the polymerisation catalyst and the cocatalyst. The preferred polymerisation catalyst is a metallocene complex and the preferred porous support is silica. The resultant supported catalysts are stable over long periods of time. The supported catalyst are particularly suitable for use in the gas phase.

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Kamfjord, et al., “Supported metallocene catalysts prepared by impregnation of MAO modified silica by a metallocene/monomer solution”, Macromolecular Rapid Communications, 19, No. 10, pp. 505-509, (1998).
Rytter, et al., “Supported Metallocene Catalysts Prepared by Impregnation of Silica with Metallocene/Aluminoxane/1-Hexene Solutions”, Macromolecular Rapid Communications, 22, No. 17, pp. 1427-1431, (2001).

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