Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Patent
1997-10-29
1999-10-12
Wu, David W.
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
526160, 526161, 526172, 526901, 526943, 502103, 502117, 502154, 502155, C08F 444, B01J 3100
Patent
active
059656778
ABSTRACT:
A catalyst component which is especially useful in so-called "slurry" or "gas phase" olefin polymerizations and which comprises an organometallic complex of a group 4 metal (having a cyclopentadienyl-type ligand and a phosphinimine ligand) and a particulate support. The catalyst component forms an excellent catalyst system when combined with an activator such as an aluminoxane or a so-called "substantially non-coordinating anion". In a preferred embodiment the organometallic complex and the activator are both deposited on the particulate support.
REFERENCES:
patent: 4897455 (1990-01-01), Welborn, Jr.
patent: 5077255 (1991-12-01), Welborn, Jr.
patent: 5153157 (1992-10-01), Hlatky et al.
patent: 5198401 (1993-03-01), Turner
patent: 5352749 (1994-10-01), DeChellis et al.
patent: 5473028 (1995-12-01), Nowlin et al.
patent: 5534474 (1996-07-01), Becker et al.
patent: 5557023 (1996-09-01), Somogyvari et al.
patent: 5625016 (1997-04-01), Schiffino et al.
Cyclopentadienyl Titanium Complexes with Aryldiasenido or Phosphiniminato-Ligands by J.R. Dilworth, Journal of Organomettalic Chemistry, 159 (1978) 47-52.
Synthese and Reaktionen von (.eta..sup.5 -Pentamethylcyclopentadienyl)- und (n.sup.5 Ethyltetramethylcyclopentadienyl)titantrifluorid by S. Mansheeh et al, Chem. Ber., 1993 136, 913-919.
Neue Komplexe des Titans mit silylierten Aminoiminophosphoran- und Sulfodiimidliganden by R. Hasselburg et al, Leitschright fur Anorganishe und allegemeine Chemis, 619 (1993) 1543-1550.
Poster Presentation by J.C. Stewart and D.W. Stephan, Dept. of Chemistry & Biochemistry, The University of Windsor, at the IDW Conference at McGill University in Nov. 1996.
Phosphaniminato-Komplexe des Titans, Syntheses und Kristallstruckturen von CpTiCl.sub.2 (NPMe.sub.3), [TiCl.sub.3 (NPMe.sub.3)].sub.2,Ti.sub.2 Cl.sub.5 (NPMe.sub.2 Ph).sub.3 und [Ti.sub.3 Cl.sub.6 (NPMe.sub.3).sub.5 ][BPh.sub.4 ]by T. Rubenstahl et al, Zeitschrift fur anorganische und allegemeine Chemie, 620(1994) 1741-1749.
Synthesis and Reactivity of Aminobis(dioxyanylamino)phosphanes by G. Shick et al, Chem. Ber., 1996, 129, 911-917.
Stewart et al., Early Transition Metal-Phosphinimine Complexes: Synthesis, Characterization and Catalytic Activity in Olefin Polymerization, text of public presentation given at University of Windsor, Ontario, Canada, pp. 1-9, Nov. 1996.
Harrison Daryll G.
Stephan Douglas W.
Stewart Jeff C.
Johnson Kenneth H.
NOVA Chemicals (International ) S.A.
Rabago Roberto
Wu David W.
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