Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing
Patent
1996-01-30
1999-01-19
Bell, Mark L.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Organic compound containing
502103, 502104, 502107, 502108, 502117, 502151, 502152, 502158, 556 52, 556 53, 526160, 526943, B01J 3100, B01J 3700, C08F 402, C08F 460
Patent
active
058613528
ABSTRACT:
A solid catalyst component for the polymerization and copolymerization of ethylene and alpha- olefins, containing a metallocene supported on an inorganic solid carrier constituted by a porous silicon oxide, the supported metallocene having the formula (I): ##STR1## wherein M is a group of metal, R' and R" are dialkylamide groups, R'" has the same definition as R' or is a cyclopentadienyl consisting ligand, and A is an anion containing an .eta..sup.5 -cyclopentadienyl ring coordinated to metal M, and wherein a carbon atom of the .eta..sup.5 -cyclopentadienyl ring of anion A is covalently bonded to the surface of the porous inorganic solid carrier.
REFERENCES:
patent: 5122491 (1992-06-01), Kioka et al.
patent: 5202398 (1993-04-01), Antberg et al.
patent: 5252529 (1993-10-01), Ueda et al.
patent: 5466766 (1995-11-01), Patsidis et al.
patent: 5529966 (1996-06-01), Luciani et al.
R. Morrison and R. Boyd, "Organic Chemistry", 3ed, Allyn and Bacon, New York, pp. 456-458, 1976.
Macromolecular Rapid Communications, vol. 15, No. 2, pp. 139-143, Feb., 1994, Kazuo Soga, et al., "Highly Isospecific SiO.sub.2 -Supported Zirconocene Catalyst Activated by Ordinary Alkylaluminiums".
Macromolecular Symposia, vol. 89, No. 1297b, pp. 249-258, Jan. 1995, Kazuo Soga, et al., "Highly Isospecific Immobilized Zirconocene Catalysts Supported on Chemically Modified SiO.sub.2 ".
Macromolecular Chemistry and Physics, vol. 195, No. 10, pp. 3347-3360, Oct. 1994, Kazuo Soga, et al., "Polymerization of Propane with Highly Isospecific SiO.sub.2 -Supported Zirconocene Catalysts Activated with Common Alkylaluminiums".
Ballato Evelina
Gila Liliana
Lugli Gabriele
Proto Antonio
Vigliarolo Diego
Bell Mark L.
Enichem S.p.A.
Pasterczyk J.
LandOfFree
Supported metallocene catalyst for olefins (co)polymerization does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Supported metallocene catalyst for olefins (co)polymerization, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Supported metallocene catalyst for olefins (co)polymerization will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-1246502