Supported metallocene-alumoxane catalysts for the preparation of

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502103, 502117, 502132, 526160, 526943, B01J 3100, B01J 3700, C08F 402, C08F 460

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059142898

ABSTRACT:
The present invention relates to the production of high density polyethylene homopolymers or copolymers having a broad and monomodal molecular weight distribution wherein the polymerization process is conducted in the presence of supported metallocene-alumoxane catalysts wherein the metallocene is bridged, comprises at least a hydrogenated indenyl or fluorenyl and a metal M which may be Ti, Zr or Hf, wherein a plurality of conformers of the metallocene are formed and isolated on the support by reaction of the metallocene with the alumoxane and depositing the product formed on the support at a temperature in the range 85.degree. C. to 110.degree. C.

REFERENCES:
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patent: 5036034 (1991-07-01), Ewen
patent: 5234878 (1993-08-01), Tsutsui et al.
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patent: 5276208 (1994-01-01), Winter et al.
patent: 5594081 (1997-01-01), Uchino et al.
"Polymerization of Propene with Zirconocene-Containing Supported Catalysts Activated by Common Trialkylaluminiums", Soga et al., Makromolekulare Chemie, vol. 194, No. 6, pp. 1745-1755 (Jun. 1, 1993).

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