Supported catalyst complexes for olefin in polymerization

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526130, 526133, 526160, 526943, 502103, 502120, 502117, 502128, C08F 4643

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057635471

ABSTRACT:
A supported catalyst composition comprising a complex of a Group 4 metal cyclopentadienyl derivative reacted with silica treated with an aluminoxane demonstrates improved reactivity, especially for incorporating long chain alpha-olefins and also shows improved resistance to catalyst poisoning. The supported catalyst composition is adapted to produce homogeneous polymers, copolymers, terpolymers, etc., for example, homogeneous polyethylene, homogeneous poly(ethylene-octene) copolymers and the like. The invention further includes the process of preparing the supported catalyst compositions and a process for preparing olefinic polymers using these catalyst compositions.

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