Supersaturation coating of cathode substrate

Electrolysis: processes – compositions used therein – and methods – Electrolytic coating – Utilizing fused bath

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204 67, C25D 904, C25C 306

Patent

active

052270459

ABSTRACT:
This invention relates to a process of electrowinning molten aluminum from alumina dissolved in molten fluoride salts which is essentially cryolite. More specifically the process relates to the treatment of aluminum reduction cell drained solid cathode surfaces to protect them while they are wetted by molten aluminum metal. This process produces aluminum wetted protective coatings composed of titanium diboride and titanium carbide and other refractory metal borides and carbides on top of a carbon-titanium diboride materials layer on the cathode surfaces from supersaturated dissolved elements in electrowon aluminum. The resulting protective coating is resistant to erosion, chemical attack, and penetration by molten aluminum metal, sodium, and cryolite electrolyte contained in that cell.

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