Sulfur trioxide sulfonation of aromatic chloroformates

Organic compounds -- part of the class 532-570 series – Organic compounds – Four or more ring nitrogens in the bicyclo ring system

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544384, 544399, 546722, 546790, 546301, 546342, 548544, 548547, 548551, 548556, 548573, 548271, C07D71142, C07D71146, C07C14376

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049855611

ABSTRACT:
A process is described for obtaining sulfophenyl quaternary ammonium or phosphonium substituted carbonic acid esters. These esters are prepared through sulfonation with sulfur trioxide of aromatic chloroformates followed by reaction of the sulfonated aromatic chloroformate with quaternary ammonium or phosphonium substituted alcohols. The resultant sulfophenyl esters are useful as bleach precursors in combination with peroxygen compounds such as sodium perborate or percarbonate.

REFERENCES:
patent: 4686061 (1987-08-01), Nollet et al.
patent: 4751015 (1988-06-01), Humphreys et al.
patent: 4788316 (1988-11-01), Thornthwaite et al.
patent: 4818426 (1989-04-01), Humphreys et al.
Gilbert, "Sulfonation and Related Reactions", Interscience Publishers, pp. 80-81, 1965.

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