Sulfur tolerant molten carbonate fuel cell anode and process

Chemistry: electrical current producing apparatus – product – and – Having earth feature

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429 16, 429 19, 429 17, 502315, H01M 814, H01M 818

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049257455

ABSTRACT:
Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

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patent: 4009321 (1977-02-01), Baker et al.
patent: 4247604 (1981-01-01), Marianowski et al.
patent: 4548876 (1985-10-01), Bregoli
An Update of the Sulfur Tolerance of Molten Carbonate Fuel Cells, L. G. Marianowski, presented at Third Annual Contractors Meeting on Contaminant Control in Hot Coal Derived Gas Streams, May 23-26, 1983.
Effects of Sulfur on Molten Carbonate Fuel Cells, S. W. Smith, H. R. Kunz, W. M. Vogel, S. J. Szymanski, United Technologies Corporation, Power Systems Division Montreal, Canada, May 1982.
Development of Molten Carbonate Fuel Cell Power Plant Technology, DOE/ET/15440-8 Quarterly Technical Progress Report No. 8, for Department of Energy, Feb., 1983.
The Effect of Sulfur on the Anodic H.sub.2 (Ni) Electrode in Fused Li.sub.2 CO.sub.3 -K.sub.2 CO.sub.3 at 650.degree. C., W. M. Vogel and S. W. Smith, J. Electrochem. Soc. 129 (7) 1441-1445 (1982).
Effects of Sulfur-Containing Gases on the Performance of Molten Carbonate Fuel Cells, T. E. Tank, T. D. Claar, and L. G. Marianowski, Interim Report EM-1699 prepared for Electric Power Research Institute by Institute of Gas Technology, Feb. 1981.
Development of Sulfur-Tolerant Components for the Molten Carbonate Fuel Cells, A. F. Sammels, S. B. Nicholson and P. G. P. Ang, J. Electrochem. Soc. 127, 350 (1980).
Development of Sulfur-Tolerant Components for Second-Generation Molten Carbonate Fuel Cells, T. D. Claar, L. G. Marianowski and A. F. Sammells, Interim Report EM-1114, prepared for the Electric Power Research Institute by Institute of Gas Technology, Jul., 1979.

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