Sulfur removal and comminution of carbonaceous material

Fuel and related compositions – Coal treating process or product thereof – Removal of undesirable

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44 51, C10L 1000

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active

047753870

ABSTRACT:
Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

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Utz; "Molten Hydroxide Coal Desulfurization Using Model Systems"; ACS Symposium Series No. 319; Fossil Fuels Utilization: Environmental Concerns.
Gravimelt Process Development, Final Report, TRW Energy Development Group, U.S. DOE Contract No. DE-AC22-81PC42295, pp. 1-8 (1983).
Boron, "Prospects for Chemical Coal Cleaning," 1983 Society of Mining Engineers Fall Meeting.
Narain, "Explosive Comminution," Quarterly Report-Apr.-Jun. 1986, Pittsburgh Energy Technology Center.
Mathur et al., "Explosive Comminution of Coal, " Proceeding of the Direct Utilization AR & TD Meeting Sep. 22, 1987.

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