Sulfur dioxide removal process

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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Details

423422, 423428, C01B 1700, C01D 700, C01D 1508, C01D 1722

Patent

active

040791190

ABSTRACT:
There is disclosed a process for reducing the loss of sodium values in a system for removing sulfur dioxide from a gas by the use of an absorption-desorption cycle employing aqueous sodium sulfite as the essential absorption solution. Sodium sulfate and/or sodium thiosulfate build-up in the system is avoided and the loss of sodium values reduced by subjecting sodium sulfate and/or sodium thiosulfate-containing material to chemical reduction to form a product containing a substantial amount of sodium carbonate. Preferably, the reduced product is subjected to carbonation followed by reaction of the bicarbonate and bisulfide components of the mixture to give a resulting liquid which is more suitable for use in the absorption-desorption process. By-product gases can be incinerated to produce sulfur dioxide-containing gases which can be charged to the sulfur dioxide absorption zone. Sodium thiosulfate can be purged from the absorption-desorption system by treating a purge stream from the desorption zone of the process.

REFERENCES:
patent: 3401010 (1968-09-01), Guerrier
patent: 3728433 (1973-04-01), Urban
patent: 3790660 (1974-02-01), Earl
patent: 3932587 (1976-01-01), Granthan et al.
patent: 3966891 (1976-06-01), Renault et al.
patent: 3971844 (1976-07-01), Schneider

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