Sulfonate compound and fluorescent probe using the same

Organic compounds -- part of the class 532-570 series – Organic compounds – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C549S344000, C549S388000, C549S392000, C549S393000

Reexamination Certificate

active

07491832

ABSTRACT:
The present invention provides a sulfonate compound including a structure represented by a general formula (I) below.In the formula (I), an atomic group A-O is an atomic group that forms a fluorescent compound upon cleavage of a covalent bond with a sulfonyl group. There may be one or plural atomic groups B—SO3— bound to an atomic group A. B is a ring substituted by one or plural electron-withdrawing groups. The electron-withdrawing group includes at least one selected from the group consisting of halogens, a carboxyl group, a carbamoyl group, a straight or branched alkylcarbamoyl group, a straight or branched alkanoyl group, a straight or branched alkoxycarbonyl group, a straight or branched alkyl halide group, and —NR3+group (the three Rs each denote a hydrogen atom or a straight or branched alkyl group and may be the same or different). When there are plural Bs, the Bs may be the same or different.

REFERENCES:
patent: 4618622 (1986-10-01), Schlecker et al.
patent: 5453461 (1995-09-01), Heiliger et al.
patent: 5576424 (1996-11-01), Mao et al.
patent: 5684040 (1997-11-01), Grabowski et al.
patent: 5986094 (1999-11-01), Ghoshal et al.
patent: 6130101 (2000-10-01), Mao et al.
patent: 6-281581 (1994-10-01), None
patent: 2000-316598 (2000-11-01), None
patent: 98/39317 (1998-09-01), None
patent: 98/39319 (1998-09-01), None
Maeda et al. Angew. Chem. Int. Ed. 2004, 43, 2389-2391.
Nakano, M., “Detection of Active Oxygen Specics in Biological Systems”, Cellular and Molecular Neurobiology, vol. 18, No. 6, 1998, 565-579.
Murrant, et al., “Detection of Reactive Oxygen and Reactive Nitrogen Species in Skeletal Muscle”, Microscopy Research and Technique, 55:236-248 (2001).
Tarpey, et al., “Methods of Detection of Vascular Reactive Species”, Circ Res. 2001;89:224-236.
Münzel, et al., “Detection of Superoxide in Vascular Tissue”, Arterioscler Throb Vasc Biol. 2002;22:1761-1768.
Esposti, M.D., “Measuring mitochondrial reactive oxygen species”, Methods 26 (2002) 335-340.
Rothe, et al., “Flow Cytometric Analysis of Respiratory Burst Activity in phagocytes with Hydroethidine and 2′, 7′Dichlorofluorescin”, Journal of Leukocyte Biology 47:440-448 (1990).
Carter, et al., “Intracellular hydrogen peroxide and superoxide anion detection in endothelial cells”, Journal of Leukocyte Biology 55:253-258 (1994).
Bindokas, et al., “Superoxide Production in Rat Hippocampal Neurons: Selective Imaging with Hydroethidine”, The Journal of Neuroscience, Feb. 15, 1996, 16(4): 1324-1336.
Al-Mehdi, et al., “Intracellular generation of reactive oxygen species during nonhypoxic lung ischemia”, The American Physiological Society, 1997, 272, L294-L300.
Benov, et al., “Critical Evaluation of the Use of Hydroethidine as a Measure of Superoxide Anion Radical”, Fee Radical Biology & Medicine, vol. 25, No. 7, pp. 829-831, 1998.
Fukuyama, et al., “2,4-Dinitrobenzenesulfonamides: A Simple and Practical Method for the Preparation of a Variety of Secondary Amines and Diamines”, Tetrahedron Letters, vol. 38, No. 33, pp. 5831-5834, 1997.
Maeda, et al., “Hydrogen Peroxide-Induced Deacetylation of Acetyl Resorufin as a Novel Indicator Reaction for Fluorometric Detection of Glucose Using Only Glucose Oxidase”, Chem. Pharm. Bull. 49(3) 294-298 (2001).
Maeda, et al., “Assessment of Acyl Groups and Reaction Conditions in the Competition between Perhydrolysis and Hydrolysis of Acyl Resorufins for Developing an Indicator Reaction for Fluorometric Analysis of Hydrogen Peroxide”, Chem. Pharm. Bull. 50(2) 169-174 (2002).
Maeda, et al., “Development of Fluorescent Probe Specific to Hydrogen Peroxide or Superoxide”, on line Jul. 8, 2003, bmas lecture summery, Retrieval day Aug. 6, 2004, www10.showa-u.ac.jp/-bmas/proceedings/III-9.pdf (w/full translation).
Delzenne, et al., Photosensitive polymers I.-Synthesis and Properties of Coumarin-modified Polymers, Industrie Chimique Belge, 1967, 21, 373-378.
Esayan, et al., “Esters of sulfonic acids, SI. Synthesis and Acricidal Propertis of Some P-chlorobenzenesulfonic Acid Esters” Izvestiya akademii Nauk Armyanskoi SSR, Khimicheskie Nauki, 1962, vol. 15, 285-289.
Rendenbach-Müller, et al., “Synthesis of Coumarins as Subtype-Selective Inhibitors of Monoamine Oxidase”, Bioorganic & Medicinal Chemistry Letter, vol. 4, No. 10, 1195-1198, 1994.
Matsu-ura, et al., “Blood glucose determination with an acetyl resorufin-glucose oxidase system as a fluorometirc indicator reaction”, Bunseki Kagaku, vol. 50, No. 7, 475-479 (2001).

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Sulfonate compound and fluorescent probe using the same does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Sulfonate compound and fluorescent probe using the same, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Sulfonate compound and fluorescent probe using the same will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4138342

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.