Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Sulfur or compound containing same
Patent
1991-02-11
1993-01-26
Shine, W. J.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Sulfur or compound containing same
585671, B01J 27053
Patent
active
051822474
ABSTRACT:
Normal olefins such as n-butene can be converted to branched species by skeletal isomerization over catalysts containing solid acids prepared by sulfating catalyst precursors containing hydrous metal oxides--e.g., aluminas, silica-aluminas or clays treated with sulfuric acid, metal sulfates, sulfur trioxide or organic sulfates. The catalyst precursors are sulfated sufficiently to produce the desired skeletal isomerization without substantial cracking under suitable isomerization conditions.
REFERENCES:
patent: 3268609 (1966-08-01), Nixon
patent: 4722986 (1988-02-01), Young
patent: 5036035 (1991-07-01), Baba et al.
Browne James E.
Kuhlmann Erven J.
Martin Kevin J.
Pascoe James R.
Kulason Robert A.
Mallare Vincent A.
O'Loughlin James J.
Shine W. J.
Texaco Inc.
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