Sulfate removal from chlorate liquor

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Alkali metal

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423499, 423475, 423659, 204 95, 23302T, C01D 314, C01B 1112

Patent

active

051087227

ABSTRACT:
Disclosed is a method of removing sulfate ion from an aqueous sodium chlorate liquor. A crystallization temperature is selected between about -15.degree. and about 0.degree. C. and the maximum concentration of sodium chlorate that is soluble in the liquor at that temperature is determined. The liquor is diluted so that the concentration of sodium chlorate in the liquor is less than that miximum concentration and the liquor is cooled to that temperature so that the sulfate ion in the liquor crystallizes as sodium sulfate decahydrate but the sodium chlorate does not crystallize.

REFERENCES:
patent: 4702805 (1987-10-01), Burkell et al.
Seidell, "Solubilities Inorganic and Metal-Organic Compounds," 4th Ed., vol. 2, 1958, p. 985.
Occidental Chemical Corporation, Chlorates brochure, "Hooker Sodium Chlorate Product Information Manual," 1977, p. 36.
Perry et al., Chemical Engineer's Handbook, Fifth Edition, McGraw Hill Book Co., 1973, pp. 17-18 thru 17-11.
In re McCarthy et al., 846F2.d77, Mar. 8, 1988.

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