Sulfamoyl compounds and agricultural and horticultural...

Drug – bio-affecting and body treating compositions – Designated organic active ingredient containing – Heterocyclic carbon compounds containing a hetero ring...

Reexamination Certificate

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C544S112000, C514S384000, C514S323000, C514S300000, C548S266800, C546S201000, C546S121000

Reexamination Certificate

active

06620812

ABSTRACT:

TECHNICAL FIELD
The present invention relates to novel sulfamoyl compounds, and agricultural chemicals (insecticides, fungicides, herbicides, plant growth controlling agents and the like.), particularly agricultural and horticultural fungicides.
BACKGROUND ART
JP-A-3-170464, JP-A-6-32785, JP-A-7-2803 and JP-A-7-215971 describe that certain sulfamoyl compounds have bactericidal activities.
Even the compounds described in the above-described early publications are unsatisfactory in potency and residual effectiveness, thus developments of more useful agricultural and horticultural fungicide have been desired.
DISCLOSURE OF THE INVENTION
Under the circumstances, the present inventors have made extensive research with a view to developing excellent fungicide and, as a result, have found that novel sulfamoyl compounds have remarkable controlling activity as agricultural and horticultural fungicide, thus accomplishing the present invention.
That is, the present invention relates to [1] to [38].
[1] A sulfamoyl compound of the general formulae (1):
wherein
R
1
and R
2
are each independently C
1-4
alkyl, or R
1
and R
2
together are C
4-6
alkylene or C
4-6
alkyleneoxy,
Y is H, halogen, C
1-8
alkyl, C
1-8
alkoxy, C
1-8
alkylthio, C
1-8
haloalkyl, C
1-8
haloalkoxy or C
1-8
haloalkylthio,
A is
B is A-1 to A-10, or
W is a chemical bond or O,
V is O or S,
D, E, F and G are each independently N, CR
7
, CR
8
, CR
9
or CR
10
, and
R
3
, R
4
, R
5
, R
6
, R
7
, R
8
, R
9
, R
10
and R
11
are each independently H, C
1-8
alkyl, C
3-8
cycloalkyl, C
2-8
alkenyl, C
5-8
cycloalkenyl, C
2-8
alkynyl, C
1-8
alkoxy, C
3-8
cycloalkyloxy, C
5-8
cycloalkenyloxy, C
2-8
alkenyloxy, C
2-8
alkynyloxy, C
1-8
alkylthio, C
3-8
cycloalkylthio, C
5-8
cycloalkenylthio, C
2-8
alkenylthio. C
2-8
alkynylthio, C
1-8
haloalkyl, C
1-8
haloalkoxy, C
1-8
haloalkylthio, C
2-8
haloalkenyl, C
2-8
haloalkenyloxy, C
2-8
haloalkenylthio, C
2-8
haloalkynyl, C
2-8
haloalkynyloxy, C
2-8
haloalkynylthio, phenyl which may be substituted (the kinds of substituent include halogen, C
1-8
alkyl, C
1-8
haloalkyl, C
1-8
alkoxy, C
1-8
haloalkoxy, C
1-8
alkylthio, C
1-8
haloalkylthio, C
1-6
alkylsulfoxy, C
1-6
alkylsulfonyl, CN, NO
2
and C
1-6
alkoxycarbonyl, the number of the substituents is 1 to 5, and the substituents may be identical or different.), phenyl C
1-4
alkyl which may be substituted, benzylthio which may be substituted, benzyloxy which may be substituted, phenoxy C
1-4
alkyl which may be substituted, phenoxy which may be substituted, phenylthio C
1-4
alkyl which may be substituted, phenylthio which may be substituted, benzoyl which may be substituted, benzoyl C
1-4
alkyl which may be substituted, benzoyloxy which may be substituted, benzoyloxy C
1-4
alkyl which may be substituted, naphthyl which may be substituted, 5- or 6-membered heterocyclic ring which may be substituted, C
1-8
hydroxyalkyl, C
1-8
hydroxyhaloalkyl, C
1-6
alkoxy C
1-4
alkyl, C
1-6
haloalkoxy C
1-4
alkyl, C
1-6
haloalkylthio C
1-4
alkyl, C
1-10
dialkoxy C
1-4
alkyl, C
1-3
alkylenedioxy C
1-4
alkyl, C
1-6
alkylthio C
1-4
alkyl, C
1-10
dialkylthio C
1-4
alkyl, C
1-3
alkylenedithio C
1-4
alkyl, C
1-6
alkoxycarbonyl, C
1-6
haloalkoxycarbonyl, C
1-6
alkoxyoxalyl, CHO, CO
2
H, C
1-6
alkoxycarbonyl C
1-4
alkyl, C
1-6
haloalkoxycarbonyl C
1-4
alkyl, NH
2
, C
1-6
alkylamino, C
1-6
alkylcarbonylamino, C
1-6
alkylcarbonylamino C
1-4
alkyl, C
1-6
haloalkylcarbonylamino, C
1-6
haloalkylcarbonylamino C
1-4
alkyl, C
1-6
alkoxycarbonylamino, C
1-6
alkoxycarbonylamino C
1-4
alkyl, C
1-6
alkylsulfonylamino, C
1-6
alkylsulfonylamino C
1-4
alkyl, C
1-6
haloalkylsulfonylamino, C
1-6
haloalkylsulfonylamino C
1-4
alkyl, C
1-6
dialkylamino, C
1-6
dialkylamino C
1-4
alkyl, C
1-6
dialkylaminocarbonyl, C
1-6
dialkylaminocarbonyl C
1-4
alkyl, C
2-6
alkyleneimino, C
2-6
alkyleneimino C
1-4
alkyl, C
2-6
alkyleneiminocarbonyl, C
2-6
alkyleneiminocarbonyl C
1-4
alkyl, C
1-6
alkylcarbonyl, C
1-6
alkylcarbonyloxy, C
1-6
haloalkylcarbonyl, C
1-6
haloalkylcarbonyloxy, C
1-6
alkylcarbonyl C
1-4
alkyl, C
1-6
alkylcarbonyloxy C
1-4
alkyl, C
1-6
haloalkylcarbonyl C
1-4
alkyl, C
1-6
haloalkylcarbonyloxy C
1-4
alkyl, hydroxyimino C
1-4
alkyl, C
1-6
alkoxyimino C
1-4
alkyl, C
1-6
alkylcarbonyloxyimino C
1-4
alkyl, C
1-6
alkylsulfonyloxyimino C
1-4
alkyl, C
1-6
alkylsulfoxy, C
1-6
haloalkylsulfoxy, C
1-6
alkylsulfoxy C
1-4
alkyl, C
1-6
haloalkylsulfoxy C
1-4
alkyl, C
1-6
alkylsulfonyl, C
1-6
haloalkylsulfonyl, C
1-6
alkylsulfonyl C
1-4
alkyl, C
1-6
haloalkylsulfonyl C
1-4
alkyl, C
1-6
alkylsulfonyloxy, C
1-6
haloalkylsulfonyloxy, C
1-6
alkylsulfonyloxy C
1-4
alkyl, C
1-6
haloalkylsulfonyloxy C
1-4
alkyl, C
1-6
haloalkoxysulfonyl, C
1-6
haloalkoxysulfonyl C
1-4
alkyl, C
1-6
dialkylsulfamoyl, C
1-6
dialkylsulfamoyl C
1-4
alkyl, C
1-6
alkoxysulfonyl, C
1-6
alkoxysulfonyl C
1-4
alkyl, C
2-6
cyanoalkyl, CN, C
1-6
thiocarbamoyl, C
1-6
nitroalkyl, NO
2
or halogen, or
two of R
3
, R
4
, R
5
, R
6
, R
7
, R
8
, R
9
, R
10
and R
11
together are C
1-3
alkylenedioxy which may be substituted, or C
3-6
alkylene.
[2] A sulfamoyl compound described in [1] above, in which A is A-1.
[3] A sulfamoyl compound described in [1] above, in which A is A-2.
[4] A sulfamoyl compound described in [1] above, in which A is A-3.
[5] A sulfamoyl compound described in [1] above, in which A is A-4.
[6] A sulfamoyl compound described in [1] above, in which A is A-5 or A-6.
[7] A sulfamoyl compound described in [1] above, in which A is A-7 or A-8.
[8] A sulfamoyl compound described in [1] above, in which A is A-9 or A-10.
[9] A sulfamoyl compound described in [1] above, in which B is B-1.
[10] A sulfamoyl compound described in [1] above, in which B is B-2.
[11] A sulfamoyl compound described in [1] above, in which B is B-3 or B-4.
[12] A sulfamoyl compound described in [1] above, in which B is B-5.
[13] A sulfamoyl compound described in [1] above, in which B is B-6 or B-7.
[14] A sulfamoyl compound described in [1] above, in which B is B-8 or B-9.
[15] A sulfamoyl compound described in [1] above, in which B is B-10.
[16] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is C
1-8
alkylthio.
[17] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is C
1-8
alkyl.
[18] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is C
1-8
haloalkyl.
[19] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is halogen.
[20] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is H.
[21] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-1, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and R
3
is CN.
[22] A sulfamoyl compound described in [1] above, in which R
1
and R
2
are Me, Y is H, W is a chemical bond, A is A-2, D, E, F and G are CR
7
, CR
8
, CR
9
or CR
10
, and any of R
3
, R
4
, R
5
and R
6
is H.
[23] A sulfamoyl compound described in [1] above, in which

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