Cleaning and liquid contact with solids – Apparatus – With plural means for supplying or applying different fluids...
Reexamination Certificate
2001-11-14
2004-03-16
Stinson, Frankie L. (Department: 1746)
Cleaning and liquid contact with solids
Apparatus
With plural means for supplying or applying different fluids...
C134S100100, C134S102100, C134S102300, C134S902000
Reexamination Certificate
active
06705331
ABSTRACT:
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to an apparatus for applying cleaning process to various substrates such as a semiconductor wafer, a glass substrate for a liquid crystal display, a PDP (Plasma Display Panel) substrate or a glass substrate and a ceramic substrate for magnetic discs.
2. Description of the Background Art
A process of manufacturing semiconductor devices includes a step of forming a thin film on a semiconductor wafer (hereinafter referred to as “substrate”) and then selectively removing the thin film through etching process, which is repeated to obtain fine patterns on the substrate. Respective surfaces of the substrate, in particular, the major surface of the substrate on which thin films are to be formed, should be clean to precisely obtain the fine patterns on the substrate. Accordingly, a step of cleaning the substrate is conducted as required.
In a conventional substrate cleaning apparatus, a droplet-injection cleaning system, which uses a cleaning double fluids nozzle for strongly removing contaminants adhering the surface of the substrate, has been proposed.
FIG. 6
is a schematic drawing of a cleaning apparatus in which the conventional cleaning double fluids nozzle is used. This cleaning apparatus is provided with a cleaning cup
51
, a spin chuck
52
for holding a substrate W inside the cleaning cup
51
, an electric motor
53
for rotating this spin chuck
52
, a gas supplying means
55
for supplying pressurized gas to the cleaning double fluids nozzle
60
for discharging droplets onto the surface of the substrate W, and a liquid supplying means
56
for supplying a pressurized liquid to the cleaning double fluids nozzle
60
. Moreover, a robot arm
57
for holding and shifting the cleaning double fluids nozzle
60
is installed.
FIG. 7
shows a cross-sectional view of the conventional cleaning double fluids nozzle
60
. The cleaning double fluids nozzle is provided with a first tube path
61
through which gas is transmitted, and a second tube path
62
the tip of which is allowed to penetrate the side wall of the first tube path
61
from the outside of the first tube path
61
, and extended to the inside of the first tube path
61
and through which a fluid is transmitted. The tip of the second tube path
62
is extended in the same direction as the direction in which the first tube path
61
is extended.
A substrate W is fixed to the spin chuck
52
, and rotated at a predetermined number of revolutions. Pressurized gas is supplied from a gas supplying means
55
to the cleaning double fluids nozzle
60
, and a pressurized liquid is supplied from a liquid supplying means
56
thereto, respectively. In the cleaning double fluids nozzle
60
, the gas and the liquid are mixed with each other so that the liquid is changed to droplets in the form of mist. These droplets are accelerated by the gas flow inside the first tube path
61
, and discharged from the tip of the first tube path
61
. The atomized droplets thus discharged are made to collide with the surface of the substrate W, thereby removing the contaminants adhering to the surface of the substrate W.
However, in the above-mentioned cleaning apparatus, the gas and the liquid are mixed inside the cleaning double fluids nozzle
60
. Therefore, when the flow rate of one fluid is attempted to be changed independently of the flow rate of the other fluid, the latter is also changed since the respective pressures interfere with each other inside the first tube path
61
.
In other words, in the case when the gas flow rate is increased so as to increase the cleaning strength, since the pressure of the gas inside the first tube path
61
increases so that the flow rate of the liquid supplied from the second tube path
62
is suppressed. Consequently, the droplets to be discharged from the tip opening of the nozzle of the double fluids nozzle
60
tend to have cleaning strength different from the initial cleaning strength due to the suppressed liquid flow rate.
Consequently, fine particles such as dusts and slurries tend to remain on the surface of the substrate W, resulting in a serious problem of a reduced yield in the manufacturing process of the semiconductor device.
Moreover, in the above-mentioned cleaning apparatus, since the gas and the liquid are mixed inside the cleaning double fluids nozzle
60
, dusts are generated because irregularities on the inner wall of the nozzle
60
are cut. The dusts may be also generated during the mixing operation. The substances resulting from the dried liquid and adhering to the inside of the nozzle
60
are taken off by the flow in the nozzle.
SUMMARY OF THE INVENTION
The present invention is directed to an apparatus for removing pollution from a substrate.
According to the present invention, the apparatus comprises: a) a liquid discharging mechanism for discharging liquid into an open space; and b) a gas discharging mechanism for discharging gas in a vicinity of the liquid in the open space to convert the liquid into liquid droplets and generate mixture of the gas and the liquid droplets, the mixture of the gas and the liquid droplets being applied to a surface of a substrate to clean the surface of the substrate.
In an aspect of the present invention, the liquid and the gas are collided with each other in the open space to obtain the mixture of the gas and the liquid droplets.
Preferably, the mixture is obtained by discharging one of the liquid and the gas into a jet flow of the other of the liquid and the gas.
In a preferred embodiment of the present invention, the liquid discharging mechanism has a liquid outlet through which the liquid is discharged, the gas discharging mechanism has a gas outlet through which the gas is discharged, and an angle between a center axis line of the liquid outlet and a center axis line of the gas outlet is not less than 0 degrees and not more than 110 degrees.
In an another aspect of the present invention, an apparatus for removing pollution from a substrate comprising: a) first and second supply paths for supplying liquid and gas, respectively; and b) a nozzle coupled to the first and second supply paths for mixing the liquid with the gas to obtain a cleaning fluid and applying the cleaning fluid onto a surface to the substrate, comprising b-1) a liquid outlet through which the liquid is discharged in an open space, and b-2) a gas outlet through which the gas is discharged into the liquid in the open space to convert the liquid into liquid droplets, the cleaning fluid being mixture of the gas and the liquid droplets in the space.
In another aspect of the present invention, an apparatus for removing pollution from a substrate, the apparatus comprising: a) first and second supply paths for supplying liquid and gas, respectively; and b) a nozzle structure, comprising: b-1) a liquid nozzle for receiving the liquid to discharge liquid flow into an open space; and b-2) a member surrounding the liquid nozzle such that a gas passage through which the gas passes is defined between the member and the fluid nozzle, gas flow being discharged through the gas passage in a direction converging at a portion defined in the open space, wherein the liquid flow is exposed to the gas flow in the open space to obtain gas-liquid mixture to be applied to the substrate.
Accordingly, an object of the present invention is to effectively remove fine particles from the surface of the substrate.
Another object of the present invention is to clean the substrate.
Still another objective of the present invention is to improve the structure of a nozzle for discharging cleaning fluid.
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patent: 4787404 (1988-11-01), Klosterman et al.
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patent: 52-62964 (1977-05-01), None
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patent: 3-131
Hirae Sadao
Morinishi Kenya
Sato Masanobu
Yasuda Shuichi
Dainippon Screen Mfg. Co,. Ltd.
McDermott & Will & Emery
Stinson Frankie L.
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