Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...
Reexamination Certificate
2006-08-08
2006-08-08
Lu, Caixia (Department: 1713)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Polymers from only ethylenic monomers or processes of...
C526S133000, C526S348000, C526S351000, C526S172000
Reexamination Certificate
active
07087690
ABSTRACT:
New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
REFERENCES:
patent: 4297465 (1981-10-01), Smith
patent: 5026798 (1991-06-01), Canich
patent: 5064802 (1991-11-01), Stevens et al.
patent: 5153157 (1992-10-01), Hlatky et al.
patent: 5318935 (1994-06-01), Canich et al.
patent: 5385993 (1995-01-01), Fujita
patent: 5453410 (1995-09-01), Kolthammer et al.
patent: 5599761 (1997-02-01), Turner
patent: 5616664 (1997-04-01), Timmers et al.
patent: 5631391 (1997-05-01), Canich
patent: 5637660 (1997-06-01), Nagy et al.
patent: 5763556 (1998-06-01), Shaffer et al.
patent: 5866665 (1999-02-01), Shaffer et al.
patent: 5985356 (1999-11-01), Schultz et al.
patent: 6030917 (2000-02-01), Weinberg et al.
patent: 6034240 (2000-03-01), LaPointe
patent: 6043363 (2000-03-01), LaPointe et al.
patent: 6103657 (2000-08-01), Murray
patent: 6121182 (2000-09-01), Okumura et al.
patent: 6214939 (2001-04-01), Shinozaki et al.
patent: 6239236 (2001-05-01), Morini et al.
patent: 6260407 (2001-07-01), Petro et al.
patent: 6706829 (2004-03-01), Boussie et al.
patent: 2004/0110910 (2004-06-01), Arjunan
patent: 0 277 004 (1988-08-01), None
patent: 0 622 380 (1994-11-01), None
patent: 0 748 824 (1996-12-01), None
patent: 0 889 061 (1999-01-01), None
patent: 1 041 092 (2000-10-01), None
patent: 1 195 391 (2002-04-01), None
patent: 1 340 694 (1973-12-01), None
patent: 00 239313 (2000-09-01), None
patent: 01-011111 (2001-01-01), None
patent: 01-048909 (2001-02-01), None
patent: 01-048910 (2001-02-01), None
patent: 01-048911 (2001-02-01), None
patent: 01-048925 (2001-02-01), None
patent: 01 048936 (2001-02-01), None
patent: 01-181331 (2001-07-01), None
patent: WO 93/05082 (1993-03-01), None
patent: WO 93/25590 (1993-12-01), None
patent: WO 94/00500 (1994-01-01), None
patent: WO 98/03521 (1998-01-01), None
patent: WO 98/10014 (1998-03-01), None
patent: WO 98/22514 (1998-05-01), None
patent: WO 99/01460 (1999-01-01), None
patent: WO 99/05186 (1999-02-01), None
patent: WO 99/06413 (1999-02-01), None
patent: WO 99/29742 (1999-06-01), None
patent: WO 00/20427 (2000-04-01), None
patent: WO 00/37511 (2000-06-01), None
patent: WO 00/50470 (2000-08-01), None
patent: WO 01/38062 (2001-05-01), None
patent: WO 01/40325 (2001-06-01), None
patent: WO 01/40330 (2001-06-01), None
patent: WO 03/040201 (2003-05-01), None
patent: WO 2004/026921 (2004-04-01), None
Bercaw et al., J. Am. Chem. Soc., vol. 118, pp. 11988-11989, (1996).
Bercaw et al., J. Am. Chem. Soc., vol. 121, pp. 564-573, (1999).
Brintzinger et al., Angew. Chem. Int. Ed. Engl., vol. 34, pp. 1143-1170, (1995).
Coates et al., Angew. Chem. Int. Ed., vol. 39, pp. 3626-3629, (2000).
Coates, G.W., Chem. Rev. vol. 100, pp. 1223-1252, (2000).
Gibson et al., Angew. Chem. Int. Ed., vol. 38, pp. 428-447, (1999).
Jordan, Adv. Organometallic Chem., vol. 32, pp. 325-351, (1991).
Lapointe et al., J. Am. Chem. Soc., vol. 122, pp. 9560-9561, (2000).
Luongo, J.P., J. Appl. Polym. Sci., vol. 3, pp. 302-309, (1960).
Organometallics, vol. 18, pp. 3649-3670, (1999).
Piers et al., J. Am. Chem. Soc., vol. 121, pp. 3244-3245, (1999).
Resconi et al., Chem. Rev. vol. 100, pp. 1253, 1345, (2000).
Sundell, T. et al., Polymer, vol. 37, pp. 3227-3231, (1996).
Kang, Kap Ku et al., “The Synthesis and Polymerization Behavior of Bimetallic Pyridine Diamide Complexes Containing Transition Metal”, J. Polym. Sci., Part A: Polym. Chem., vol. 37(20), pp. 3756-3762, (1999).
Ziniuk, Zeev et al., “Zirconium Complexes of Chelating Dianionic Bis (Pentafluorophenylamido) Ligands: Synthesis, Structure and Ethylene Polymerization Activity”, Inorg. Chem. Commun., vol. 2(11), pp. 549-551, (1999).
U.S. Appl. No. 09/992,789, filed Nov. 2001.
U.S. Appl. No. 09/992,148, filed Nov. 2001.
U.S. Appl. No. 09/992,385, filed Nov. 2001.
U.S. Appl. No. 09/992,760, filed Nov. 2001.
U.S. Appl. No. 09/992,630, filed Nov. 2001.
U.S. Appl. No. 09/992,031, filed Nov. 2001.
Resconi et al., “Selectivity in Propene Polymerization with Metallocene Catalysts”,Chem. Rev. 2000, 100, 1253-1345.
Boussie Thomas R.
Diamond Gary M.
Goh Christopher
Hall Keith A.
Lapointe Anne M.
Lu Caixia
Symyx Technologies Inc.
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