Substituted porphyrins, porphyrin-containing polymers, and synth

Details Substituted porphyrins, porphyrin-containing polymers, and synth Substituted porphyrins, porphyrin-containing polymers, and synth

1992-08-14

1994-12-06

Shah, Mukund J.

Organic compounds -- part of the class 532-570 series

Organic compounds

Radioactive metal containing

534 15, 540145, C07D48722, C01F 1700, C01G 5500

Patent

active

053711998

ABSTRACT:
Porphyrins substituted with, for example, vinyl and acetylene groups are provided, along with polymers containing the same. In preferred embodiments, the substituted porphyrins are prepared by coupling halogenated porphyrins with carbon-centered anionic groups via metal-mediated crosscoupling reactions under stoichiometric or catalytic conditions.

REFERENCES:
patent: 3687863 (1972-08-01), Wacher
patent: 3897255 (1975-07-01), Erickson
patent: 3899334 (1975-08-01), Erickson
patent: 4360703 (1982-11-01), Bolton et al.
patent: 4647478 (1987-03-01), Formanek et al.
patent: 4668670 (1987-05-01), Rideout et al.
patent: 4792836 (1988-12-01), Quinlan
patent: 4895682 (1990-01-01), Ellis et al.
patent: 4957615 (1990-09-01), Ushizawa et al.
patent: 4986256 (1991-01-01), Cohen et al.
patent: 4988808 (1991-01-01), Morgan et al.
patent: 5164944 (1992-11-01), Benton et al.
patent: 5171741 (1992-12-01), Dougherty
patent: 5252730 (1993-10-01), Mackey
Callot, Chemical Abstracts, vol. 81, 1974 Abstract 105479p.
Yang et al. Chemical Abstracts, vol. 105, 1986 Abstract 180709f.
Pandey, R. K., et al., Tetrahedron Letters, 1990, 31, 7399-7402.
Maruyama, et al., Bull. Chem. Soc. Jpn., 1990, 63, 170-175.
Nagata, T., et al., J. Am. Chem. Soc., 1990, 112, 3054-3059.
Vicente et al., J. Org. Chem., 1991, 56, 4407-4418.
Wallace, et al., Tetrahedron Letters, 1990, 31, 7265-7268.
Pandey, R. K., et al., Tetrahedron Letters, 1990, 31, 789-792.
Pandey, R. K., et al., Tetrahedron Letters, 1992, 33, 5315-5318.
Helms, A., et al., J. Am. Chem. Soc., 1992, 114, 6227-6238.
Morris, I. K., et al., J. Am. Chem. Soc., 1990, 50, 1231-1236.
Rodriguez, J., J. Am. Chem. Soc. 1991, 113, 1652-1659.
Nudy, Louis R., et al., Tetrahedron, 1984, 40, 2359-2363.
Gonsalves, Rocha, d'A. A. M. et al., J. Heterocyclic Chem., 1985, 22, 931.
Bonnett, R., "Nomenclature," The Porphyrins, Dolphin, ed., vol. I, Academic Press, New York, 1978.
Mauzerall D., "The Porphyrinogens," The Porphyrins, Dolphin, ed., vol. I, Academic Pressi, New York, 1978.
Kim, et al., "Synthesis of Porphyrins from Monopyrroles," The Porphyrins, Dolphin, ed., vol. III, Academic Press, New York, 1978.
Paine, "Synthesis of Pyrroles and of Porphyrins via Single-Step Coupling of Dipyrrolic Intermediates," The Porphyrins, Dolphin, ed., vol. III, Academic Press, New 1978.
Johnson, A. W., "Synthesis of Porphyrins from 1,19-Dideoxybiladienes--ac and 1,19-Dideoxybilenes-b," The Porphyrins, Dolphin, ed., vol. III, Academic Press, New 1978.
Kumada, M., Pure & Appl. Chem., 1980, 52, 660-679.
Collman, J. P. et al., "University Science Books," 1987 Chapter 14, Mill Valley, Calif.
Hayashi, T., et al., Tetrahedron Letters, 1979, 21, 1871-1874.
Stein, C. A. et al., Cancer Research, 1988, 2659-2668.
Lindsey, Jonathan S., et al. J. Org. Chem., 1987, 52, 836.
Cohen, Jack S., "Use of Paramagnetic Metalloporphyrins as Contrast Agents for Tumors in NMR Imaging," (Feb. 1985). U.S. Department of Commerce, Springfield Va. 22161.
Manka, John S., et al., Tetrahedron Letters, 1989, 30, 7341-7344.
Wytko, Jennifer A., et al., J. Org. Chem., 1992, 57, 1015-1018.
Lindsey, Jonathan S., et al., J. Org. Chem., 1988, 54, 828-836.
Clezy, P. S., et al., "Synthesis of Porphyrins from Oxobilane Intermediates," The Porphyrins, Dolphin, ed., vol. III, Academic Press, New York, 1978.
DiNello, Robert K., et al., "Isolation and Modification of Natural Porphyrins," The Porphyrins, Dolphin, ed., vol. III, Academic Press, New York, 1978.
Godquin-Giroud Anne-Marie et al., "Metallomesogens: Metal Complexes in Organized Fluid Phases," Angew. Chem. Int. Ed. Engl. 30 (1991), 375-402.
Lehn, Jean-Marie, "Angewandte Chemie International Edition in Engish," vol. 27, No. 1, (Jan. 1988), pp. 89-112.
Wasielewski, Michael R., Chem. Rev, 1992, 92, 435-461.
Patai and Rapport, "The Chemistry of Functional Groups, Supplement C," part 1, pp. 529-534, Wiley, N.Y. (1983).
Eglinton and McCrae, Adv. Org. Chem. 4, 225-328, (1963).
Anderson, H. L. Tetrahedron Letters, 1992, 33, 1101-1104.
Arnold et al., "Some Reactions of Meso-Formyloctaethylporphyrin", J.C.S. Perkin I, pp. 366-370. 1986.
Komarov et al., "Synthesis and Some Transformations of .alpha.-Siliconacetylenic Aldehydes", UDC, pp. 920-922 1965.
Hevesi, et al., J. Org. Chem., 1991, 56, 4407-4418.
Gunter et al., Aust. J. Chem., 1990, 43, 1839-60.
Patai and Rapport, "The Chemistry of Functional Groups Supplement C", Chapter 13, pp. 513 (1983).
Osuka, et al., Angew. Chem. Int. Ed. Engl., 1991, 30, 582.
Groves, et al., J. Am. Chem. Soc., 1983, 105, 5791.
Mansuy, et al., J. Chem. So. Chem. Commun., 1985, 155-156.
Durand et al., J. Am. Chem. Soc., 1983, 105, 2710-2718.
Minnetian, O. M., J. Org. Chem., 1989, 54, 5567-5574.

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