Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acids and salts thereof
Patent
1979-02-14
1980-10-07
Garner, Vivian
Organic compounds -- part of the class 532-570 series
Organic compounds
Carboxylic acids and salts thereof
560 82, 2603405R, 560104, 560105, 2604105, 560109, 560122, 260556AR, 560130, 560145, 260562R, 560146, 562430, 260577, 562433, 562434, 568308, 562435, 562463, 568315, 424 45, 424282, 424308, 424309, 424311, 424312, 424313, 424317, 424321, 424324, 424330, 424331, 544171, 560 1, 560 12, 560 19, 560 20, 560 21, 560 48, 560 51, 560 53, 560 62, 560 73, 560 80, C07C 6538, C07C 6976, C07C 8762, C07C10342, C07C14378
Patent
active
042270154
ABSTRACT:
Aryl substituted diketones and keto-esters, useful as antiviral agents and insecticides, are prepared by reacting an arylalkyl or arylalkenyl iodide with a metal salt of the appropriate diketone or keto-ester. The intermediate iodides are prepared by condensing a methyl cyclopropyl ketone with an aromatic aldehyde to give an arylvinyl cyclopropyl ketone, reducing the latter to an arylethyl cyclopropyl carbinol or arylvinyl cyclopropyl carbinol, treating the carbinol with phosphorus tribromide and then with zinc bromide to give an arylalkyl or arylalkenyl bromide, and then replacing the bromine atom by iodine.
REFERENCES:
patent: 3553226 (1971-01-01), Kaiser et al.
patent: 3891674 (1975-06-01), Diana et al.
Johnson et al., J.A.C.S., 90, 6225-6226, 1968.
Garner Vivian
Johnson Thomas L.
Sterling Drug Inc.
Wyatt B. Woodrow
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