Substituted naphthopyrans

Compositions – Light transmission modifying compositions – Displaying color change

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549389, 549331, 549 60, 549 58, 548525, 548454, 5483644, 5483114, 546196, 546164, 544375, 544150, 524110, 524109, 524 90, 524 84, C08K 515, C07D31178, C07D40502, G02B 523

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056585012

ABSTRACT:
Described are novel reversible photochromic 2H-naphtho[1,2-b] pyran compounds, examples of which are compounds having certain substituents at the number 5 carbon atom of the naphtho-portion of the naphthopyran and at the 2-position of the pyran ring. Certain substituents may also be present at the number 6, 7, 8, 9 or 10 carbon atoms of the naphtho portion of the naphthopyran. Also described are organic host materials that contain or that are coated with such compounds. Articles such as ophthalmic lenses or other plastic transparencies that incorporate the novel naphthopyran compounds or combinations thereof with complementary photochromic compounds, e.g., spiro(indoline) type compounds, are also described.

REFERENCES:
patent: 3562172 (1971-02-01), Ono et al.
patent: 3567605 (1971-03-01), Becker
patent: 3578602 (1971-05-01), Ono et al.
patent: 3627690 (1971-12-01), Casella et al.
patent: 4215010 (1980-07-01), Hovey et al.
patent: 4342668 (1982-08-01), Hovey et al.
patent: 4637698 (1987-01-01), Kwak et al.
patent: 4816584 (1989-03-01), Kwak et al.
patent: 4818096 (1989-04-01), Heller et al.
patent: 4826977 (1989-05-01), Heller et al.
patent: 4880667 (1989-11-01), Welch
patent: 4931219 (1990-06-01), Kwiatkowski et al.
patent: 4980089 (1990-12-01), Heller
patent: 4994208 (1991-02-01), McBain et al.
patent: 5066818 (1991-11-01), Van Gemert
patent: 5200116 (1993-04-01), Heller
patent: 5238981 (1993-08-01), Knowles
patent: 5244602 (1993-09-01), Van Gemert
patent: 5274132 (1993-12-01), Van Gemert
patent: 5384077 (1995-01-01), Knowles
patent: 5405958 (1995-04-01), Van Gemert
patent: 5411679 (1995-05-01), Kumar
Friedel-Crafts and Related Reactions, George A. Olah, Interscience Publishers, vol. 3 Chapter XXXI, pp. 1-8, 1964.
"Regioselective Friedel Crafts Acylation of 1,2,3,4-Tetrahydroquinoline and Related Nitrogen Heterocycles: Effects of NH Protective Groups and Ring Size", Ishihara, Y., et al., J. Chem. Soc., Perkin Trans. 1, pp. 3401-3406, 1992.
The Chemistry of Quinonoid Compounds, S. Patai, John Wiley & Sons, Inc. Part 2, Chapter 17 (The Addition and Substitution Chemistry of Quinone) pp. 877-1144, 1980.
"Regioselective 6-Amination and 6-Arylation of 5,8-Quinolinedione Promoted by Metal Ions", Yoshida, K., et al, Bull. Chem. Soc. Jpn., vol. 61, 1988, pp. 4335-4340.
"Reaction of 1,4-Naphthoquinone with N-methylpyrrole. Selective Synthesis of Pyrrolyated 1,4-Naphthoquinones", Yoshida, K., et al, Chemistry Express, vol. 5, No. 10, 1990, pp. 749-752.
"The Reaction of Trialkylboranes with 1,4-Naphthoquinone: A New, Convenient Synthesis of 2-Alkyl-1,4-Naphthalenediols. Evidence for a Free-Radical Chain Mechanism", Kabalka, G., J. Organomet. Chem., 33, 1971, pp. C25-C28.
"Catalytic Asymmetric Induction in Oxidation Reactions. Synthesis of Optically Active Epoxynaphthoquinones", Pluim, H., et al, J. Org. Chem. 1980, 45, pp. 2498-2502.
"Synthesis and Properties of 6-Substituted Quinoline-5,8-dione Colour Formers", Yoshida, K., et al, J. Chem. Soc. Perkin Trans. I, 1994, pp. 2521-2523.
"Arylation of Quinones with Arenes and Palladium Acetate", Itahara, T., J. Chem. Soc., Chem. Commun., 1981, pp. 859-860.
"Reaction of Hydroxylamines with 1,4-Quinones: A New Direct Synthesis of Aminoquinones", Bittner, S., et al, Synthesis, Sep. 1994, pp. 917-919.
"Selective Synthesis and Metallochromic Properties of Pyrrolylated Quinoline-5,8-diones", Yoshida, K., et al, J. Chem. Soc., Perkin Trans. I, 1992, pp. 2713-2715.
Organic Synthesis, vol. 31, John Wiley & Sons, Inc., pp. 90-93, 1951.
Organic Synthesis, vol. 31, John Wiley & Sons, Inc., pp. 72-77, 1951.
"Fast Fading Naphtho[1,2-b]pyran Photochromics", Research Disclosure, May 1994, pp. 267-268.

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