Plant protecting and regulating compositions – Antidotes – Hetero ring containing antidote
Patent
1994-09-14
1996-05-14
McKane, Joseph K.
Plant protecting and regulating compositions
Antidotes
Hetero ring containing antidote
504271, 548247, 548248, 548110, A01N 4372, C07D26102
Patent
active
055167500
ABSTRACT:
Substituted isoxazolines, process for their preparation, compositions containing them, and their use as safeners.
Compounds of the formula (I) and salts thereof, ##STR1## in which R.sup.1 is carboxyl, formyl or another acyl radical or a derivative of the last-mentioned 3 groups,
R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.18 -alkyl, C.sub.3 -C.sub.8 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, C.sub.2 -C.sub.8 -alkynyl, C.sub.1 -C.sub.18 -alkoxy, C.sub.2 -C.sub.8 -alkenyloxy, C.sub.2 -C.sub.8 -alkynyloxy, C.sub.1 -C.sub.18 -alkylthio, C.sub.2 -C.sub.8 -alkenylthio, each of the last-mentioned 9 radicals in each case being unsubstituted or substituted, or (C.sub.1 -C.sub.8 -alkoxy)carbonyl, and
R.sup.3 and R.sup.4 independently of one another are an aliphatic, araliphatic or heteroaraliphatic radical having 1 to 30 carbon atoms which is unsubstituted or substituted by one or more functional groups, or
an aromatic or heteroaromatic radical which is unsubstituted or substituted,
are suitable as safenets for pesticides, preferably herbicides, in crop plants. The compounds can be prepared from alkenes (II) and nitrile oxides (III) by the process of claim 6.
REFERENCES:
patent: 3274210 (1966-09-01), Fritsch et al.
patent: 4808750 (1989-02-01), Rogers et al.
patent: 4988812 (1991-01-01), Kim et al.
patent: 5314863 (1994-05-01), Loher et al.
patent: 5332715 (1994-07-01), Loher et al.
Journal of Indian Chemical Society, Bd. 70, No. 2, Feb. 1993, Calcutta, pp. 134-137, A. Nagarajan et al., entitled "Electron-Impact Mass Spectral Fragmentation Patterns of Isoxazolines".
Chemical Abstracts, vol. 67, No. 21, Nov. 20, 1967, Columbus, Ohio, Abstract No. 100039W, V. A. Tartakovskii et al., entitled "1-3 Dipolar Cycloaddition Unsaturated Compounds", p. 9407.
Chemical Abstracts, vol. 120, No. 11, Mar. 14, 1994, Columbus, Ohio, Abstract No. 134457j, p. 1040.
Angewandte Chemie, International Edition, Band 18, No. 1, 1979, pp. 78-79, Volker Jager et al., entitled "Ring-Opening of 5-(bromomethyl)-2-isoxazolines to Beta, Gamma-Enoximes", pp. 77-79.
CA86:72623d 3-Isoxazolyl isocyanates. Sumimoto et al., p. 616,1977.
CA119:219557w Acyclic acids . . . properties Witek et al., p. 341, 1993.
J. Am. Chem. Soc. Bd. 46 (1924), p. 791.
J. Org. Chem. Bd. 25 (1960), p. 1160.
Bauer Klaus
Bieringer Hermann
Willms Lothar
Hoechst Schering AgrEvo GmbH
McKane Joseph K.
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