Substituted bicyclooctenemethanols

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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260586G, C07C 3522, C07F 302

Patent

active

041669169

ABSTRACT:
The use of unsaturated bicyclooctenemethanols to augment or enhance the organoleptic properties of perfumes, tobaccos and perfumed articles and particularly the aroma of perfumes and perfumed articles and the aroma and taste of tobaccos, together with compositions containing such bicyclooctenemethanols and processes for preparing them, said bicyclooctenemethanols having the generic structures: ##STR1## wherein the wavy line represents exo or endo configurations of the ethanol moiety with respect to the carbon-carbon double bond of the bicyclooctene moiety; and intermediates useful in processes for preparing such bicyclooctenemethanols which intermediates have the structures: ##STR2## wherein X is a halogen selected from the group consisting of chlorine, bromine and iodine.

REFERENCES:
patent: 3255254 (1966-06-01), Kauer
patent: 3337498 (1967-08-01), Hogsed et al.
patent: 3515740 (1970-06-01), Frampton
patent: 3879466 (1975-04-01), Light
patent: 3914332 (1975-10-01), Chappell et al.
patent: 4062878 (1977-12-01), Pesnelle et al.
patent: 4064184 (1977-12-01), Light et al.
Bates et al., "J. Org. Chem.", 34:2615 (1969).
"Nippon Kogaku Zasohi", 1971, 92(10), 874-876.

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